环保型钝化液的制备及性能研究汇编.docVIP

环保型钝化液的制备及性能研究 姜祖林，高琦，刘颖 （大连工业大学 ，辽宁 大连 116034）Environmentally friendly passivation solution preparation and performance of the research JIANG Zu-lin, GAO Qi, LIU Ying (Institute of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian, 116034，China) Abstract: This paper prepares a kind of silane passivation solution consisting of silicone resin and inorganic metal, which can form organic-inorganic hybrid membrane on the surface of aluminum. Besides, this paper also studies the influence of passivation solution concentration, and the proportion of PH, silicone resin, and polyurethane resin on corrosion resistance of hybrid membrane. In addition, an infrared spectrum analysis was carried out on the hybrid membrane with the aid of Fourier transform infrared spectrometer，and the microscopic morphology of hybrid membrane is characterizedby using SEM scanning electron microscopy as well. Meanwhile, the hybrid membrane is measured by electrochemical experiments, and the corrosion resistance performance of hybrid membrane in different conditions is also explored by utilizing open circuit voltage, alternating impedance and tafel polarization curve. The result shows that the higher the passivation solution concentration, the better the performance of corrosion resistance, and that the corrosion resistance of hybrid membrane is better when PH tends to 3.9 ,the ratio of silicone resin is about 21% and the ratio of polyurethane resin is about 6%. Key words:silane passivation solution；hybrid membrane；silicone resin；polyurethane resin；corrosion resistance世界每年因锈蚀而损失的金属数量巨大，防止金属锈蚀已成为科学研究中的重大问题。环保涂料的制备与使用可有效解决金属锈蚀问题[1-4]。环保材料的发展与应用使金属表面铬化处理技术逐渐被硅烷钝化技术替代[5-6]，对于铝合金表面处理技术来说，硅烷溶胶凝胶技术越来越受到人们的重视[7]，硅烷钝化技术主要形成Si-O-Al转换层覆盖在铝合金表面，防止其腐蚀杂化膜[8-9]，不但可以形成致密的膜，还有很强的吸附力[10-12]，但是不足的是没有很强的机械强度，因此加入少量的金属离子使其具有良好的机械性能[13-14]。笔者制备了有机无机杂化膜，并对杂化膜的耐腐蚀性能以及表面形貌进行了表征。 1 实验部分 1.1 主要试剂 硝酸铈，分析纯，天津市光复精细化工研究所生产；六氟锆酸，分析纯，阿拉丁化学试剂有限公司生产；硝酸铝，分析纯，国药集团化学试剂有限公司生产；硝酸锰，分析纯，国药集团化学试剂有限公司生产；氯化锌，分析