过共晶高硼铸钢组织细化研究.pdfVIP

摘 要 5.多组元复合变质对初生硼化物具有更好的细化作用。0.9%Nb +0.4%RE 复 合变质不仅可以细化初硼化物，还可以使其横截面的形状由四边形的尖角变成圆 角，可以有效减小由凝固和外力引起的应力集中。这主要是由于曲率小的晶体部 分在高温凝固过程中溶解所致。0.9%Nb +0.4%RE 复合变质还可以使组成初生相 颗粒的晶簇之间发生粘合而生成单一的柱状晶体，使系统的表面能下降。 6.随着热处理温度的提高，包晶硼化物、初生硼化物依次溶解，在 1050℃时， 包晶硼化物完全溶解，初生硼化物部分溶解由四方柱状变为骨状。稀土元素可以 有效地提高硼化物的高温稳定性，使其溶解温度提高，且含量越高效果越显著。 由于初生硼化物具有非常好的高温稳定性，利用热处理工艺很难改变其形态和分 布。 关 键 词：过共晶高硼铸钢；细化；变质；合金化；热处理 论文类型：应用基础研究 II ABSTRACT Subject: Study in the Technology of Microstructure Refinement in Hypereutectic High Boron Cast Steels Specialty: Materials Physics and Chemistry Name: Ge Hui-jun Supervisor: Zhu Yao-min ABSTRACT Due to existence of hard and coarse primary borides, the toughness of hypereutectic high boron cast steels as well as their abrasion resistance at high impact conditions is decreased definitely, which limits its application in industrial conditions. In this paper, inoculating treatment, suspension casting and alloying treatment were used to refine the primary Fe B borides and the peritectic Fe (C,B) borides in the 2 3 hypereutectic high-B cast steel. The results were drawn as follows: The dimension of the primary borides was refined as well as the morphology of the peritectic was altered in the hypereutectic high-boron cast steel(the HFBC alloy) after modified by the rare earth ferrosilicon and potassium/sodium salts.The contents of modifier at 0.6%RE or 0.3%K/Na have a maximum refinement making the primary seperately from 81.4µm undisposed to 30.4 µm and 23.4µm. It was found that RE can purify molten steel by eliminating sulfur and oxygen. CeB andCeO S can rifine the