邻苯二甲酸二辛酯的合成 步婷论文.doc

邻苯二甲酸二辛酯的合成研究 摘 要 邻苯二甲酸二辛酯(DOP) 是一种最广泛使用的增塑剂，具有良好的综合性能，增塑效率高，挥发性较低，低温柔软性较好，耐热性和耐候性良好2-乙基己醇)和邻苯二甲酸酐（苯酐）为原料，在催化剂作用下合成增塑剂邻苯二甲酸二辛酯(DOP)。分别以氧化铝、氧化锌、乙酸锌、辛酸亚锡、对甲苯磺酸5种单体催化剂及其以一定比例相互复配的乙酸锌/对甲苯磺酸、辛酸亚锡/氧化铝、氧化锌/氧化铝、辛酸亚锡/氧化锌4种复配催化剂合成DOP，考察催化剂对合成DOP的影响，结果表明，氧化铝与辛酸亚锡以1∶1比例复配为最佳催化剂，并考察了反应条件对合成DOP 的影响，结果表明，在异辛醇与苯酐摩尔比3∶1，辛酸亚锡/氧化铝复配催化剂用量分别占反应物总量的0.2%，反应温度230℃，反应时间2.5 h的最佳工艺条件下，反应物酯化率达91.79%。 关键词: 邻苯二甲酸二辛酯 催化剂 反应温度 醇酐摩尔比 Study of the Synthesis of dioctyl phthalate Abstract Dioctyl phthalate (DOP) is one of the most widely used plasticize, high plasticizing efficiency, low volatility, good low temperature flexibility, good heat resistance and weatherability, and has good prospects for industrialization. In this paper,using isooctanol (2 - ethylhexyl alcohol) and phthalic anhydride (phthalic anhydride) as raw materials, DOP is syntheticed with a catalyst. Respectively, alumina, zinc oxide, zinc acetate, zinc octoate, stannous, p-toluenesulfonic acid monomers catalyst and complex with each other to a certain percentage of zinc acetate / p-toluenesulfonic acid, stannous octoate / alumina, alumina / zinc oxide, zinc oxide / stannous octoate the complex catalyst synthesis DOP. Study shows that alumina and stannous octoate catalyst mixed in a 1:1 ratio is the best.The reearch of reaction conditions shows that the optimum condition is isooctyl alcohol and phthalic anhydride mole ratio of 3:1, the stannous tin / alumina complex catalyst amount, respectively, accounting for 0.2% of the total amount of reactants, the reaction temperature of 230 ° C, reaction time 2.5 h, the rate of esterification is 91.79%. Key words: Phthalate dioctyl phthalate；Catalyst；Reaction temperature；Alcohol anhydride more ratio 目 录 摘 要 I ABSTRACT II 第一章 绪 论 1 1.1邻苯二甲酸二辛酯的简介 1 1.1.1 邻苯二甲酸二辛酯的物性 1 1.1.2 邻苯二甲酸二辛酯的用途 1 1.2不同催化剂合成邻苯二甲酸二辛酯 2 1.2.1酸性催化合成邻苯二甲酸二辛酯 2 1.2.2钛酸酯催化合成邻苯二甲酸二辛酯 2 1.2.3氧化物催化合成邻苯二甲酸二辛酯 3 1.2.4锡类化合物催化合成邻苯二甲酸二辛酯 3 1.2.5铝酸钠催化合成邻苯二甲酸二辛酯 3 1.2.6固体酸催化合成邻苯二甲酸二辛酯 4 1.2.7杂多酸催化合成邻苯二甲酸二辛酯 4 1.2.8酸性树脂催化合成邻苯二甲酸二