活性炭改性整体催化剂上低温选择性还原NOx.pdfVIP

中国环境科学 2007，27(6)：845-850 China Environmental Science 活性炭改性整体催化剂上低温选择性还原N 唐晓龙 ，郝吉明 ，易红宏p，宁 平 ，李俊华 (1．昆明理工大学环境科学与工程学院云南昆明650093； 2．清华大学环境科学与工程系，北京 100084) 摘要：采用浸渍法制备活性炭改性整体催化剂(MnOJAC／C)，以NH3为还原剂，考察了反应温度、o2和NO体积分数等不同条件下低温选 择性催化还原N 性能，并采用XRD、TPD和BET等测试手段对催化剂进行表征．结果表明，Mn 在载体表面呈高度分散，堇青石负载了 活性炭层和Mn 后，整体催化剂的比表面积增至 88．7m ／g；NO吸附量显著提高，1 50*CNO转化率50％,NO转化率在22012时达最大值 97％，200~280~C均高于80％；在低温时提高反应气氛中的O2和NO体积分数均可明显提高NO转化率；在确保活性组分分散度的前提下提 高Mn 负载量将利于进一步提高催化剂的低温催化活性；反应140h后整体催化剂炭层氧化损失率仅为1,25％，具有较好的稳定性． 关键词：整体催化剂；氮氧化物；氨；选择性催化还原(scR1；低温 中图分类号：X511 文献标识码：A 文章编号：1000-6923(2007)06—0845—06 Selective catalytic reduction of N with NH3 by monolithic catalyst MnOffAC／C under low temperature in the presence of excess 02． LNG Xiao．1ong ，HAO Ji．ming2 YI Hong-hong ，NING Ping ，LI Jun．hua2(1．College of ， Environmental Science and Engineering,Kunming University of Science and Technology,Kunm ing 650093，China； 2．Department of Environmental Science and Engineering，Tsinghua University，Beijing 1 00084，China)．China Environmental Science，2007，27(6)：845-850 Abstract：MnOJAC／C monolithic catalysts were prepared by impregnation AC／C with aqueous solutions of Mn(N03)2． The selective catalytic reduction(scR1 activities of monolithic catalysts for NOx with NI-I3 were tested in various conditions，and the activity variation under different experimental conditions were investigated．The BET specific area of MnO~AC／C was about 88．7m ／g．while the bared ceramic suppoa was only 5m2／g,and the adsorption of NO on MnO]AC／C enhanced greatly．The data of XRD of crushed samples showed that MnOx were in good dispersion over the catalysts．MnO~AC／C monolithic catalysts showed better activity at low temperature range than traditional vanadium type catalysts．NO conversion reached 5O％ even at l 5O℃．and more than 80％ occu~ed in the range of 200-280℃．The maximum NO conversion 97％ Was observ