煤低温氧化过程中微晶结构变化规律研究.pdfVIP

摇 第36卷第2期 煤摇 摇 炭摇 摇 学摇 摇 报 Vol.36摇 No.2摇 摇 2011年 2月 JOURNAL OF CHINA COAL SOCIETY Feb.摇 2011摇 摇 摇 文章编号:0253-9993(2011)02-0322-04 煤低温氧化过程中微晶结构变化规律研究 戴 广 龙 (1郾 安徽理工大学 能源与安全学院,安徽 淮南摇 232001;2郾 安徽理工大学 煤矿安全高效开采省部共建教育部重点实验室,安徽 淮南摇 232001) 摘摇 要:煤自燃与其微晶结构有关,利用X射线衍射分析法,研究了褐煤、气煤、气肥煤和无烟煤4 个原煤样和不同低温氧化温度下褐煤和气肥煤的微晶结构变化规律。 研究结果表明,煤的微晶结 构特征与其低温氧化之间有其内在的本质联系,煤矿物含量和微晶结构的差别,造成了它们低温氧 化能力和自燃倾向性的差别;微晶结构随变质程度的加深造成自燃倾向性和低温氧化能力逐渐降 低;层间距随氧化温度的增加而逐渐减小,芳香层片的平均直径随氧化温度的增加而逐渐增加,芳 香层片的堆砌高度随氧化的加深而逐渐增大。 关键词:煤;低温氧化;微晶结构;X射线衍射 中图分类号:TD752郾2摇 摇 摇 文献标志码:A Research on microcrystalline structure change regularity in the coal low temperature oxidation process DAI Guang鄄long (1郾School of Energy and Safety,Anhui University of Science and Technology,Huainan摇 232001,China;2郾TheKey Laboratory Being Built byAnhuiProvince andMinistry of Educationfor CoalMine Safety and Efficient Exploitation,Anhui University of Science and Techology,Huainan摇 232001,China) Abstract:Coal spontaneous combustion is related its microcrystalline structure. Using X鄄ray diffraction analysis re鄄 searched microcrystalline structure change regularity of four raw coal samples including lignite,gas coal,gas鄄fat coal and anthracite etc,and lignite and gas鄄fat coal at different low temperature oxidation temperature. Research results show that the microcrystalline structure characteristic of coalwith low temperature oxidation isthe essence of contact. The difference of coalmineralcontentandmicrocrystallinestructurecausestheability ofthelow temperatureoxidation and the self鄄ignition orientation.Microcrystalline structure being deepenedwith the degree of deterioration causes self鄄 ignition orientation andthe ability of