超临界CO2中黄1对涤纶染色的实验研究.pdfVIP

超临界CO 中黄1 对涤纶染色的实验研究 2 蒋婷，李志义，孟庭宇，刘学武，胡大鹏 （大连理工大学流体与粉体工程研究设计院，辽宁 大连 116012） 摘 要：印染工业中废水对环境造成了严重污染，因此人们在寻找一种新的工艺。近几年，超临界流 体染色备受青睐，这种工艺彻底解决水污染问题。本文对在超临界CO2 中用一种黄色分散染料（以下 称做黄 1）染涤纶进行了实验研究，考察了温度、压力和时间对染色深度（K/S值）的影响，确定了适 宜的工艺条件。实验结果显示，随着温度、压力的升高和时间的延长，染色深度（K/S值）增大，且温 度对染色深度（K/S值）的影响要比压力的影响显著。适宜的工艺条件为压力 25MPa、温度 130℃和时 间 100min。对该工艺条件下的染色结果进行牢度测试，并将之与水染（高温高压染色）结果进行比较， 结果比水染结果要好或与之相当。结果表明，超临界染色用于分散染料染涤纶可获得满意的效果。 关键词：超临界流体染色，黄 1，涤纶，染色深度（K/S 值），牢度，水染 Experimental investigation of dyeing PET fiber with yellow 1 in supercritical carbon dioxide Jiang Ting, Li Zhi-yi, Ming Ting-yu, Liu Xue-wu, Hu Da-peng (Research＆Design Institute of Fluid and Powder Engineering, Dalian University of Technology, Dalian 116012, China ) Abstract: Supercritical fluid dyeing which does not use water is a new method in textile industry in order to decrease or eliminate effluent wastewater. Supercritical carbon dioxide is a suitable solvent, which is applied to supercritical fluid dyeing processes. In this study, the dyeing of PET fiber with yellow 1 has been attempted using supercritical carbon dioxide as solvent medium in order to investigate the effect of temperature, pressure and time on the dye results. The experiments were recorded at temperatures form 80 to 130℃, pressures from 17 to 30MPa and time from 30 to 150min. The color yield of fibers was assessed by K/S measurements. It could be shown that K/S was strongly increased with the increase of temperature, pressure and time. The best condition was the working temperature of 130 ℃，pressure of 25MPa and time of 10min. Good color yield and fastness properties were obtained. Key