一种新型聚合物电解质的制备与表征.pdfVIP

一 种新型聚合物电解质的制备与表征 杜鸿昌1,2，马志刚‘ ，高建东-- ，邓正华 (1．中同科学院成都有机化学研究所，L~J rl成都610041；2．中国科学院研究生院，北京100039) 摘要：通过丙烯酸二乙二醇甲醚酯、丙烯酸和丙烯酰胺共聚，添加有机增塑剂和无机添加剂，制备了一种新型的锂离子 蓄电池复合聚合物电解质膜。用红外光谱、扫描电镜和交流阻抗谱等方法进行了表征，研究了影响电导率的各种因素、 电化学稳定性和与金属锂的界面相容，陛。该电解质膜机械加工，陛能良好，电化学性能稳定，电导率在22℃下达到了 1．27 X 10—3S／cm。研究结果表明，聚合物的组分比例、锂离子浓度、增塑剂和添加剂对电导率有不同程度的影响。以该 电解质膜组装模拟电池，具有较好的充放电，性能。 关键词：聚合物电解质；锂离子蓄电池；交流阻抗法 中图分类号：TM 912．9 文献标识码：A 文章编号：1002—087 X(2007)12—0966—05 Preparation and characterization of a novel solid polymer electrolyte DU Hong—chang‘ ，MA Zhi—gang‘：，GAO Jian—dong ，DENG Zheng—hua‘ fJ．Chengdu Institute ofOrganic Chem~try,the Chinese Academy ofSciences，Chengdu Sichuan 610041，China； 2 Gradua~School of the Chinese Academy ofSciences，Beijing 1 00039，China) Abstract： A novel solid polymer electrolyte (SPE) for lilhium ions rechargeable batteries， was prepared by copolymerizing acryl amide，acrylic acid and the organic plasticing agent， and inorganic additives were used to enhance the conductivity． The conductivity reached 1．27×1 0-3 S／cm at 22℃． Fourier transformed infrared spectroscopy(FTIR)，scanning electron micrographs(SEM)，electrochemical impedance spectroscopy(EIS)and a series of electrochemical measurements were conducted，and the conductivities factors，the interracial affinity with lilhium Of lhe electrolyte and lhe cycling performance of lhe battery were discussed． The results show lhal lhe monomers molar ratio，lithium salts content， plasticing agent and additives are dominant conductivity influencing factors．The batteries prepared with lhis SPE showed excellenl cycling performance Key words：solid polymer eleclrolyle(SPE)：lilhium ion battery；electrochemical impedance speclroscopy(ElS) 锂离子蓄电池以其高比能量和使用寿命长而受到重视，但 在此基础上研究共聚物组成比例、聚合条件、温度、增塑 是液态电解质使得电池寿命缩短，有安全隐患，因此，采用聚合