燃料电池韩子龙概要1.pptVIP

New sulfonated polybenzimidazole (SPBI) copolymer-based proton-exchangemembranes for fuel cells;A B S T R A C T; The membranes prepared from both techniques possessed desirable mechanical, chemical, thermal, and hydrolytic stability. However, the pure SPBI copolymer membranes from technique 1 exhibited very poor proton conductivities .On the other hand, the SPBI/H3PO4 blend membrane from technique 2 showed extremely high conductivities (0.1 S/cm) at high temperatures (120 8C) and low relative humidities (RHs) (even at anhydrous conditions), which has great potential to be used as high temperature and low humidity PEMs for fuel cells. ;Membrane preparation;The resulting free-standing membranes (in acid form) were thoroughly washed with de-ionized water and dried in vacuum at 90 8C overnight (Fig. 2(a)). A Mitutoyo Electronic Indicator (Model: 543-252B, Mitutoyo America Corporation, Aurora, IL) was used to measure the membrane thickness with an accuracy of 0.5 mm. The final membranes had a thickness of approximately 30 mm.;; In this period, in situ phase inversion (transition from the solution state to the gel state) of the membrane was observed during the hydrolysis of the solvent PPA (a good solvent for SPBI-1) to PA (a poor solvent for SPBI-1) since both SPBI-1 and PPA are extremely hygroscopic and the moisture could be easily absorbed to hydrolyze PPA into PA. Finally, a very uniform and flexible SPBI-1/H3PO4 blendmembrane was obtained (Fig. 2(b)). The membrane was wiped with a tissue paper to remove all remaining H3PO4 on the membrane surface and was dried in an oven at 120 8C for 10 h. The final membrane had a thickness of about 70 mm. ;Membrane characterization;1. Ion-exchange capacity The IEC was measured by means of a classical titration method. A membrane sample of about 0.200 g was soaked in 50 mL of 1.0 M NaCl solution for 2 days. The released proton concentration was titrated using a 0.01-M NaOH solution;2. Fourier transform infrared spectra T