2,4-二氯苯氧乙酸臭氧化过程中过氧化氢的生成.pdfVIP

第59卷 第 4期 化 工 学 报 Vo1．59 NO．4 2008年4月 Journal of Chemical Industry and Engineering (China) April 2008 2，4一二氯苯氧乙酸臭氧化过程中 过氧化氢的生成 陈 岚，权宇珩 (华北电力大学环境学院，河北 保定071003) 关键词；除草剂；2，4一二氯苯氧乙酸；臭氧化；过氧化氢 中图分类号：X 592；TQ 450．9 文献标识码：A 文章编号：0438—1157(2008)04～1028—04 Formation of hydrogen peroxide during ozonation of 2，4一dichl0r0phen0xyacetic acid in aqueous solution CHEN Lan。QUAN Yuheng (Department of Environmental ScienceEngineering，North China Electric Power University，Baoding 071003，Hebei，China) Abstract：The method of degradation of 2，4-dichlorophenoxyacetic acid by ozonation in a cylindrical bubbling tower reactor was proposed．It was revealed that hydrogen peroxide was detected during the ozonation of 2，4-dichlorophenoxyacetic acid．Hydrogen peroxide is useful to decompose ozone in aqueous solution to form hydroxyl radicals．Therefore， hydrogen peroxide has an effect on the 2，4一 dichlorophenoxyacetic acid degradation．In order to understand the formation of hydrogen peroxide during ozonation of 2，4-dichlorophenoxyacetic acid， the effect of various experimental parameters on the concentration of hydrogen peroxide was investigated．The experimental results showed that the formation of hydrogen peroxide depended on 2，4-dichlorophenoxyacetic acid in aqueous solution．The yield of hydrogen peroxide produced by ozone decomposition was relatively small and could be neglected．The reaction of H2 O2 decay simultaneously took place in reaction solution with the reaction of H2 O2 formation．The change of concentration of hydrogen peroxide in aqueous solution indi