钛基材上电化学沉积羟基磷灰石 - 中国表面工程.pdf

19 6 Vol.19 No.6 2006 12 CHINA SURFACE ENGINEERING December. 2006 6 47 * , 210016 (SEM)TiO X 2 (XRD)CaHPO ·2H O 4 2 TQ174.1 A 1007–9289(2006)06–0047–04 Hydroxyapatite Coatings Deposited Electrochemically on Titanium Substrate WANG Yue-qin TAO Jie (College of Material Science and Technology,Nanjing University of Aeronautics and Astronautics Nanjing 210016 China) Abstract The calcium phosphate coatings, electrodeposited on the anodized surface of Ti., were converted to hydroxyapatite coatings in alkaline solution in this work. The morphologies of titanium oxide nanotubes and hydroxyapatite were observed by means of scanning electron microscope(SEM). In addition, the phase structure and compositions of the HA coatings were determined by X-ray diffractometer(XRD).Meanwhile the bonding strength of the interface between the HA coatings and the substrate was detected. The results demonstrated that the electrochemically deposited coatings were dicalcium phosphate dihydrate (CaHPO · 2H O, DCPD), and then were transformed into hydroxyapatite after treatment with alkaline solution. The 4 2 bonding strength of the interface between HA coatings and substrate was improved when the substrate was treated by anodic oxidation or H O was used during the electrodepos