立体光造型成型材料的制备及其性能研究论文.pdf

立体光造型成型材料的制备及其性能研究 1 1,2 1 * 杨媛丽 ，王永祯 ，王爱玲 （1.中北大学机械工程系，山西 太原 030051 ； 2.太原理工大学材料科学与工程学院，山西 太原 030024 ） 摘 要：光敏树脂是光固化快速成型的关键材料。本文以环氧树脂E-51 和丙烯酸为基本原 料，合成了紫外光固化快速成型用光敏树脂，通过比较不同光敏树脂体系的固化度及显微硬 度，优化了光敏树脂合成工艺；用硅烷偶联剂处理后的SiC 纤维对光敏树脂进行了改性实验， 测试并比较了光敏树脂改性前后固化件的显微硬度和拉伸强度等机械性能。结果表明：预聚 物与单体质量比为 2:1 、光引发剂含量为 3.5%时,树脂体系固化度最高，硬度性能指标较理 想；光敏树脂经改性后，拉伸强度有大幅度提高。 关键词：光造型；固化度；SiC 纤维；显微硬度；拉伸强度 Molding Material’s Preparation of SLA and Its Performance Research YANG YUAN-li1 ,WANG Yong- zhen 1,2 , WANG Ai- ling1* (1.Dept. of Mechanical Engineering, North University of China, TaiYuan 030051, China; 2. College of Material Science and Engineering, Taiyuan University of Technology, TaiYuan 030024, China) Abstract: Photosensitive resins were the key material in the UV-curing of rapid prototyping. In this paper photosensitive resins was synthesized using raw material epoxy resin E-51 and acrylic acid, photosensitive resins mixture ratio was defined through comparing the different photosensitive resins’ state of UV-curing and microhardness; photosensitive resins were modified using disposed silane resin acceptor SiC fiber, solidification’s mechanical behavior such as microhardness and tensile-strength of photosensitive resins and modified photosensitive resins were tested and matched. The result indicates that when the mass percent of prepolymer and monomer was 2:1, content of photo-initiator was 3.5%, the photosensitive resins’ state of UV-curing was highest, performance data of degree of hardness was optimal; and the modified photosensitive resins’ tensile-strength has great improvement. Keywords: stereolithography; state of UV-curing; SiC fiber;