44二烷芳氧基甲基联苯的合成.pdf

Vol . 37 No. 3 ( ) 305 2011-06 Journal of East China U niversity of S ien e an d T e hnology ( Natural S ien e E dition) : 1006-3080( 2011) 03-0305-06 4, 4.-(/ ) 何海鸥, 杨雪艳, 吴范宏 ( 华东理工大学化学与分子工程学院, 上海200237) : 以4, 4.- 二氯甲基联苯( 4, 4.-bis( hloromethye)-biphenye, BCM B) 为原 , 通过Wil- liam son 醚合成法制备了一系列4, 4.- 二( 烷/ 芳氧基甲基) 联苯对化合物4, 4.- 二( 甲氧基甲基) 联苯4, 4.- 二( 丁氧基甲基) 联苯以及4, 4.- 二( 苯氧基甲基) 联苯的合成工艺进行改进, 缩短了反应 时间, 提高了收率, 并在此基础上合成了一系列化合物 : 4, 4.- 二氯甲基联苯; William son 醚合成法; 4, 4.- 二( 烷/ 芳氧基甲基) 联苯 : Q625. 13 : A Synthesis of 4, 4.-Bis(alkoxy/ phenoxy-methyl biphenyl) H E H ai-ou, YA N G X ue-y an, W U Fan-hong ( School of Chemistry an M olecular Eng ineering , East China Univ ersity of S cience an Technology , Shanghai 200237, China) Abstract: A series of 4, 4.-bis( alkyloxy/ phenoxy methyl biphenyl) w ere synthesized, using 4, 4.-bis ( hloromethyl)-biphenyl ( BCM B) as raw material by Williamson ether synthesis methods. T he synthesis pro ess of 4, 4.-bis ( methoxymethyl ) biphenyl, 4, 4 .-bis ( butoxymethyl ) biphenyl and 4, 4.-bis ( phenoxymethyl) biphenyl w as improved in rea tion time and yield. On the basis, a series of new ompounds w ere prepared. Key words: 4, 4.-bis( hloromethyl) biphenyl; William son ether synthesis; 4, 4.-bis( alkoxy/ phenoxy- methyl biphenyl) [ 6] 4, 4.-( 4, 4.-bis( hloromethye)- PVC biphenye, BCMB) , 4, 4.-( / )