含聚污水水质变化规律及储层伤害机理研究-海洋石油.PDF

　　　　海　洋　石　油 　　　·86 · 　　　　 OFFSHORE　OIL 　　2010 12 :1008-2336(2010)04-0086-06 1, 2 2 3 4 4 1 刘义刚 , 唐洪明, 陈华兴,李玉光 , 王　珊, 高建崇 (1.(), 300452;2., 610500;3. , 300452;4.(), 100010) 　:含聚污水的水质问题是目前聚驱注水油 最紧迫的问题之 一, 以渤海旅大10-1 油 含聚污水为例, 利用原子 力显微镜、环境扫描电镜等微观分析手段, 实验研究含聚污水中残余聚合物对悬浮物浓度和粒径 中值, 含油率以及结垢 离子浓度的具体影响, 并进行了含聚污水回注储层岩心动态损害实验。研究表明:当残余聚合物浓度由0 mg/L 时逐级 增加到 150 mg/L 时, 注入水悬浮物浓度增加了近 269.0%, 粒径中值仅增加0.3μm,抽滤速度下降了99.3%, 含油率下 降了86.5%,镁钙离子浓度下降了18.0%。残余聚合物的絮凝作用以及对纤维滤膜的吸附作用是悬浮物增加、抽滤速 度显著降低的主要原因, 乳化作用使得常规含油率测定值偏低, 且残余聚合物浓度及分子量越高, 注入水水质变化趋势 越明显。另外, 单 一残余聚合物对高渗透储层损害有限, 其与悬浮物及含油的协同作用是主要伤害源。 :;;; :TE357.6 　　:A 　　doi:10.3969/j.issn.1008-2336.2010.04.086 Study on produced water quality variation rule from polymer flooding and mechanism of formation damage 1, 2 2 3 4 4 1 Liu igang , Tang Hongming , Chen Huaxing , Li uguang , Wang Shan , Gao Jianchong (1.Tianj in Branch of CNOOC China Limited, Tangg u 300452;2.Southwest Petroleum University , Chengdu 610500; 3.CNOOC Energy Technology Serv ice-Oilf ield E ng ineering R esearch nstitute, Tanggu 300452; 4.CNOOC (China)Beij ing R esearch Center, Beij ing 100010) Abstract:The index of polymer flooding produced water is one of the most pressing issues in oilfield devel- opment.Taking LD10-1oil field in the Bohai Sea for example and taking advantage of the atomicforce mi- croscopy,environmental scanning electron microscope and other means of microscopic analysis,the influence of residual polymer on variation of suspended solids concentration and particle size,oil content and the scale- forming ions was studied.The results show that when the residual polymer concentration increased