ZIF-8石墨烯电催化.pdfVIP

Angewandte Chemie DOI: 10.1002/anie.201408990 Electrocatalysts ZIF-8 Derived Graphene-Based Nitrogen-Doped Porous Carbon Sheets as Highly Efficient and Durable Oxygen Reduction Electrocatalysts** Hai-xia Zhong, Jun Wang, Yu-wei Zhang, Wei-lin Xu, Wei Xing, Dan Xu, Yue-fei Zhang, and Xin-bo Zhang* Abstract: Nitrogen-doped carbon (NC) materials have been carbon atoms and thus improve the O2 adsorption and proposed as next-generation oxygen reduction reaction (ORR) reduction.[4] To this end, various nitrogen-containing precur- catalysts to significantly improve scalability and reduce costs, sors and templates have been employed to construct porous but these alternatives usually exhibit low activity and/or NCs.[5–11] However, the obtained catalysts show insufficient gradual deactivation during use. Here, we develop new 2D activity and poor stability due to poor electrical conductivity sandwich-like zeolitic imidazolate framework (ZIF) derived of NCs and their corrosion during ORR.[12,13] Porous metal– graphene-based nitrogen-doped porous carbon sheets organic frameworks (MOFs) are a new family of crystalline (GNPCSs) obtained by in situ growing ZIF on graphene porous materials.[14] Among them, the zeolitic imidazolate oxide (GO). Compared to commercial Pt/C catalyst, the framework (ZIF-8) with a high carbon content and large GNPCSs show com