氢对x80钢焊接接头在近中性ph值溶液中腐蚀行为的影响.pdf

第28 卷 第5 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol.28 No.5 2016 年9 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Sep. 2016 氢对X80 钢焊接接头在近中性pH 值溶液中 腐蚀行为的影响 范裕文 吴 明 陈 旭 孟向楠 王彦亮 辽宁石油化工大学石油天然气工程学院 抚顺 113001 摘要：采用动电位极化和电化学阻抗技术研究了电化学充氢后X80 钢母材和焊缝在近中性pH 值溶液中的电 化学行为，并结合光学显微镜对试样充氢前后的形貌进行了观察，测量了母材和焊缝的放氢量。结果表明，电 化学充氢并没有改变钢的组织结构；相同电化学充氢条件下，焊缝比母材吸收更多的氢。在近中性pH 值溶液 中，未充氢时母材比焊缝有更好的耐蚀性能。充氢促进母材和焊缝在近中性pH 值溶液中的阳极溶解。随充 氢时间增加，母材和焊缝的自腐蚀电位负移，腐蚀电流增大，腐蚀产物膜电阻和极化电阻减小，母材与焊缝电 化学腐蚀行为均加剧。充氢后焊缝中位错缺陷浓度高，对氢起钉扎作用的，使焊缝的耐蚀性大于母材。 关键词：X80 管线钢 焊缝 电化学充氢 腐蚀 中图分类号：TG 172.4 文献标识码：A 文章编号：1002-6495(2016)05-0415-08 Effect of Charged-hydrogen on Corrosion Behavior of Welded Joint of X80 Pipeline Steel in a Near-neutral pH Solution FAN Yuwen, WU Ming, CHEN Xu, MENG Xiangnan, WANG Yanliang College of Petroleum Engineering, Liaoning Shihua University, Fushun 113001, China Abstract: The electrochemical corrosion behavior of hydrogen- charged base metal and welded joint of X 80 pipeline steel in a near-neutral solution was studied by means of potentiodynamic po- larization and electrochemical impedance spectroscopy. The morphologies of the base metal and the welded joint of X80 pipeline steel were observed by optical microscopy and the content of re- leased-hydrogen were measured, respectively. It was found that charged-hydrogen had little effect on the microstructure of X80 pipeline steel. The hydrogen content of the welded joint is higher than that of the base metal under the same hydrogen charging condition. The base metal demonstrated higher corr