十八硫醇自组装膜对青铜-银电偶腐蚀的抑制作用.pdf

第33 卷 第3 期 中国腐蚀与防护学报 Vol.33 No.3 2013 年6 月 Journal of Chinese Society for Corrosion and Protection Jun. 2013 十八硫醇自组装膜对青铜-银电偶腐蚀的 抑制作用 1 2 2 2 2 万 俐 杜 伟 李佳佳 丁 毅 陈步荣 1. 南京博物院 南京 210016; 2. 南京工业大学材料科学与工程学院 南京 210009 摘要：采用十八硫醇(ODT) 的乙醇溶液在青铜和Ag 表面制备了自组装膜（SAMs）。通过测量青铜-银的电偶电 流和室内加速变色实验，研究了自组装前后的电偶腐蚀性能。采用XPS ，Tafel 极化曲线法和微分电容法初步 研究了ODT SAMs 的作用机理。结果表明：ODT 分子通过S 与基体形成硫醇盐，吸附在青铜和Ag 表面形成自 组装膜，该自组装膜在3.5%NaCl 溶液和含S 大气中，能够有效抑制青铜和Ag 之间的电偶腐蚀，属于混和型 缓蚀剂。 关键词：十八硫醇 自组装膜 电偶腐蚀 青铜 Ag 中图分类号：TG 172.3 文献标识码：A 文章编号：1005-4537(2013)03-0245-06 Inhibition Effects of Odtadecanethiol Self-assembled Monolayers for Bronze-silver Galvanic Corrosion 1 2 2 2 2 WAN Li , DU Wei , LI Jiajia , DING Yi , CHEN Burong 1. Nanjing Museum, Nanjing 210016, China; 2. College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China Abstract ：In order to solve the galvanic corrosion problem between bronze and silver, the self-as- semble monolayers(SAMs) of odtadecanrthiol (ODT) was prepared on the surfaces of bronze and silver. The galvanic corrosion between bronze and silver were investigated by couple corrosion cur- rent and accelerated discoloration test. Corrosion inhibition and function mechanism of ODT SAMs were investigated by X-ray photoelectron spectroscopy (XPS), polarization curves and dif- ferential capacity methods. The results showed that ODT molecular adsorbed on the s