聚乙二醇对氧化亚铁硫杆菌浸出黄铜矿的影响 - the chinese journal .pdf

第 25 卷第 7 期 中国有色金属学报 2015 年 7 月 Volume 25 Number 7 The Chinese Journal of Nonferrous Metals July 2015 文章编号：1004-0609(2015)-07-2015-07 聚乙二醇对氧化亚铁硫杆菌浸出黄铜矿的影响 张瑞洋，魏德洲，刘文刚，卢 涛，沈岩柏，崔宝玉 (东北大学 资源与土木工程学院，沈阳 110819) 摘要：为提高黄铜矿生物浸出率，研究聚乙二醇(PEG)对 Acidithiobacillus ferrooxidans strain XZ11 Fe2+氧化活性和 黄铜矿生物浸出过程的影响，并采用 SEM 和 EDS 对浸出后矿物表面形貌和相组成进行表征。结果表明：相对分 子质量大于200 的PEG 对Acidithiobacillus ferrooxidans Fe2+氧化活性具有一定的促进作用，添加 30 mg/L PEG 2000 时，浸出20 d 后，铜浸出量高达 451.70 mg/L ，较不添加FEG 时提高了 1.11 倍；添加 PEG 时，黄铜矿表面的侵 蚀面呈沟壑状，出现溶蚀坑，并生成 Fe3+ 的羟基化多聚物Fe(Ⅲ)—O—OH 。PEG 的添加提高了浸出体系中细菌浓 度和 Fe3+浓度，加速了黄铜矿的溶解。 关键词：黄铜矿；聚乙二醇；氧化亚铁硫杆菌；生物浸出；表面活性剂 中图分类号：TF111.31 文献标志码：A Effect of polyethylene glycol on chalcopyrite bioleaching with Acidithiobacillus ferrooxidans ZHANG Rui-yang, WEI De-zhou, LIU Wen-gang, LU Tao, SHEN Yan-bai, CUI Bao-yu (College of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China) Abstract: Polyethylene glycol (PEG) was used to improve the bioleaching rate of chalcopyrite by Acidithiobacillus ferrooxidans (At.f) strain XZ11. The effect of PEG on the Fe2+ oxidizing activities of Acidithiobacillus ferrooxidan and bioleaching of chalcopyrite were investigated. The surface morphologies and phase composition of chalcopyrite after bioleaching were characterized by SEM and EDS. The results show that PEG with relative molecular mass greater than 200 can promote the Fe2+ oxidizing activities of Acidithiobacillus ferrooxidan After bioleaching for 20 d, the copper extraction yield of chalcopyrite with 30 mg/L PE