电刺激条件下初始ph值对剩余污泥厌氧消化效果的影响 - 中国水网.pdf

中国环境科学 2016,36(3) ：833~839 China Environmental Science 电刺激条件下初始pH 值对剩余污泥厌氧消化效果的影响 * 陈 莹,尹常凯,朱南文 ,袁海平,楼紫阳 (上海交通大学环境科学与工程学院,上海 200240) 摘要：在厌氧消化反应器中施加 0.6V 电压刺激,考察初始 pH 值(3,5,7,9,11)对剩余污泥厌氧消化效果的影响.结果表明,当初始 pH 值为 9、 厌氧消化至 32d 时,污泥挥发性固体有机物去除率为 38.1%, 甲烷产率为 224mLCH /g VS; 同样的消化时间内,初始 pH 值为 7 的对照组,其挥 4 发性固体有机物去除率为 32.2%, 甲烷产率仅为 162mLCH /g VS.调节初始 pH 值可加速污泥水解酸化过程,其中 pH 值为 11 时,水解酸化效 4 果最好, 比其他 pH 值条件下产生更多的挥发性脂肪酸(VFAs).在产酸高峰期,初始 pH 值为 3、11 时,乙酸和丁酸是主要产物;初始 pH 值为 5、 7、9 时,主要产物是乙酸和丙酸.调节初始 pH 值能加速氨氮的释放,且 pH 值为酸性(3,5)时的氨氮浓度高于碱性条件下(9,11)的浓度. 关键词： 电刺激；初始 pH 值；剩余污泥；厌氧消化 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2016)03-0833-07 Effect of initial pH on anaerobic digestion of waste activated sludge under direct electrical stimulation. CHEN Ying, * YIN Chang-kai, ZHU Nan-wen , YUAN Hai-ping, LOU Zi-yang (School of Environmental Science and Engineering, Shanghai Jiaotong University, Shanghai 200240, China). China Environmental Science, 2016,36(3)：833~839 Abstract ：Batch tests were operated to investigate effects of initial pH (3,5,7,9,11) on anaerobic digestion of waste activated sludge under 0.6V direct electrical stimulation. Initial pH had a great influence on biogas production and VS removal efficiency. At the optimal initial pH of 9, maximum methane yield of 224mLCH4/g VS and VS removal efficiency of 38.1% were achieved after 32days digestion. Initial pH could accelerate hydrolysis and acidification process of waste activated sludge. Alkaline environment (pH 9, 11) enhanced SCOD and VFAs concentrations in suspensions, especially at pH 11. Acetic acid and butyric acid were dominant at pH 3and 11while acetic acid