废旧线路板中主要有价金属的生物反应器浸出研究.pdf

中国环境科学 2014,34(1) ：201~206 China Environmental Science 废旧线路板中主要有价金属的生物反应器浸出研究 许治国 1,朱能武 1,2*,杨 崇 1,吴平霄 1 (1.华南理工大学环境与能源学院,广东 广州 510006 ；2.工业聚集区污 染控制与生态修复教育部重点实验室,广东 广州 510006) 摘要：为探讨可供实际生物浸出应用的反应器规模废旧线路板中有价金属浸出特性和工艺条件,通过设计序批式生物浸出反应器,采用分 离到的氧化亚铁硫杆菌 Z1 作为菌种资源,在考察废旧线路板中有价金属的浸出特性的基础上,确定了反应器运行的最佳工艺条件.结果表 明,反应器运行的最佳工艺条件为曝气量 1L/min、停留时间 30h、搅拌速率 300r/min 以及粉末投加量 12g/L.在此条件下,经过 101h 可以浸 出 90.24%的铜.同时,经 197h 的浸出,可以溶出 93.06%的镁、92.00%的锌、85.59%的铝 64.51%的镍.因此,生物浸出反应器能有效回收废 旧线路板中的有价金属,为该技术的实际应用提供了实验证据. 关键词：废旧线路板；生物浸出；反应器；有价金属；氧化亚铁硫杆菌 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2014)01-0201-06 1 Study of bioreactor for mainly valuable metals recovery from waste printed circuit boards. XU Zhi-guo ,ZHU 1,2* 1 1 Neng-wu , YANG Chong , WU Ping-xiao (1.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China ；2.Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, China). China Environmental Science, 2014,34(1)：201~206 Abstract ：To explore the bioleaching characteristics and process conditions of valuable metals in bioreactor which from waste printed circuit boards so as to promote the practical application of bioleaching technology, the designed batch mode bioleaching reactor and was used and strain Thiobacillus ferrooxidans Z1 was isolated, the optimum operation conditions of bioreactor was determined on the basis of investigation of bioleaching characteristics of valuable metals from waste printed circuit boards. The results showed that the optimum operation conditions of the reactor was: aeration rate 1L/min, retention time 30h, stirr