稀土产品中钍的测定 - 中国测试.PDF

第39卷第5期 中国测试 Vol.39 No.5 2013年9月 CHINA MEASUREMENT TEST September，2013 doi院10.11857/j.issn.1674-5124.2013.05.014 稀土产品中钍的测定 朱智超 （四川省核工业辐射测试防护院，四川 成都 610503） 摘 要院为解决高含量稀土和钍的分离问题对稀土产品中钍进行测定。该方法对比酒石酸、三乙醇胺的用量，设计分 离富集工艺，采用743型大孔树脂分离稀土和钍，使用偶氮胂III 比色法测定。试样经过碱熔，水浸取加入三乙醇胺， 沉淀用盐酸（ ，用盐酸（ ，用氯化铵溶液（ 过滤。 4mol/L）溶解，在酒石酸存在下 4mol/L）淋洗杂质 20%）将树脂转化为铵型 后，再用草酸铵溶液（4%）洗脱钍。在盐酸（4mol/L）介质中，用偶氮胂III显色于波长660nm处测定。实验表明该方法 操作简便，设备简单，结果稳定，精密度和准确度高。 ；钍； ；偶氮胂 关键词院稀土产品 743型大孔树脂 III；分离富集 + 中图分类号院TG146.4曰TF125.24曰O615.2曰O633 文献标志码院A 文章编号院1674-5124渊2013冤05-0053-03 Determination of thorium in rare earth products ZHU Zhi-chao （Sichuan Radiation Detection and Protection Institute of Nuclear Industry，Chengdu 610503，China） Abstract: In order to separate thorium from the high-content rare earth and determine thorium in rare earth products，the authors studied the impact of tartaric acid，triethanolamine at different dosage，designed the routing of extraction and enrichment with macroporous resin 743 as separation materials，and thorium contents was determined by arsenazo III colorimetric method. In this method， the sample was digested with alkaline solution， extracted with aqueous triethanolamine. After it was filtered，the precipitate was dissolved with 4 mol/L hydrochloric acid. In the presence of tartaric acid，the impurities of resin was eluted with 4 mol/L hydrochloric acid，and the resin was converted to ammonium resin with 20% ammonium chloride solution，