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w a t e r r e s e a r c h 4 3 ( 2 0 0 9 ) 4 4 1 2 – 4 4 2 0 Available at www.sciencedire ct .com j o u r n a l h o m e p a g e : w w w . e l s e v i e r . c o m / l o c a t e / w a t r e s Adsorption mechanism of selenate and selenite on the binary oxide systems a b c a, Ya Ting Chan , Wen Hui Kuan , Tsan Yao Chen , Ming Kuang Wang * aDepartment of Agricultural Chemistry, National Taiwan University, Taipei, 10617, Taiwan bDepartment of Environmental and Safety Engineering, Ming-Chi University of Technology, Taipei County, 243, Taiwan cDepartment of Engineering and System Sciences, National Tsing Hua University, Hsin-Chu, 30043, Taiwan a r t i c l e i n f o a b s t r a c t Article history: Removal of selenium oxyanions by the binary oxide systems, Al- or Fe-oxides mixed with Received 6 January 2009 X-ray noncrystalline SiO2, was previously not well understood. This study evaluates the Received in revised form adsorption capacity and kinetics of selenium oxyanions by different metal hydroxides onto 29 June 2009 SiO2, and uses X-ray absorption spectroscopy (XAS) to assess the interaction between Accepted 30 June 2009 selenium oxyanions and the sorbents at pH 5.0. The binary oxide systems of Al(III)- or Published online 4 July 2009 Fe(III)-oxides mixed with SiO2 were prepared, and were characterized for their surface area, point of zero charge (