原创力文档Application of model of ideal solution of interaction products (ISIP) and thermodynamic modeling (TM) for description of superconducting phases in the system YBaCuO：（应用理想溶液模型的交互产品(ISIP)和热力学建模(TM)的描述超导系统YBaCuO阶段）.pdfVIP
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Journal of Thermal Analysis, Vol. 48 (1997) 1069-1084
APPLICATION OF MODEL OF IDEAL SOLUTION OF
INTERACTION PRODUCTS (ISIP) AND
THERMODYNAMIC MODELING (TM) FOR
DESCRIFFION OF SUPERCONDUCTING PHASES IN THE
SYSTEM YBaCuO
G. Moiseev and N. Vatolin
Institute of Metallurgy,Ural Divisionof the RussianAcademyof Sciences,
101, AmundsenStr., Ekaterinburg, 620016, Russia
Abstract
The thermochemicalproperties of Cu203were calculated.The stabilityofCu203 was studied
with the help of TM methods. It was shownthat this oxide can exist in oxygen atmosphere
(P= 105Pa) at temperaturesbelow 380 K.
A variant of the ISIP model was used with TM to determinethe Cu§ Cu2+ and Cu3+ con-
tents and oxygen indexes in YBa2Cu30~ (123-Ox), YBa2Cu3.sOy (123.5-Oy), YBa2Cu40z
(124-O~), YBazCusOq (125-Oq) and YBazCu60m (126-Om) solutionsat 100-1200 K in oxygen
medium (P= 105Pa).
Methods for determinationof some thermodynamicproperties and oxygenindices are sug-
gested for a superconductorfamilyin the systemYBaCuO.
Keywords: modeling, solution, systemYBaCuO, thermodynamicproperties
Introduction
Different solution models have been proposed to describe the superconducting
phase 123-Ox (see, for example, [1-4]). As a rule, their application permits evalu-
ation of the changes in the oxygen index in the formula of this phase under various
conditions (temperature/pressure changes, interaction with different substances,
etc.). These solution models were put forward after determination (or estimation)
of the main thermochemical properties (standard enthalpy, entropy and heat capac-
ity) for the phases 123-O7 and 123-O6. The essence of the models is described in
the original papers.
In 1988 [2], when the thermodynamic properties of the phase 123-Ox were prac-
tically unknown, we attempted to use th
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