第二章第二节 分子的立体结构1.3（Chapter ii the three-dimensional structure of the second segment of the molecule 1.3）.docVIP

第二章第二节 分子的立体结构1.3（Chapter ii the three-dimensional structure of the second segment of the molecule 1.3） This article is contributed by zhoulikt The PPT document may not have a good browsing experience at the WAP end. It is recommended that you choose TXT, or download the source file to the native view. The three-dimensional structure of the second molecule The third class Examples 1: the following types of central atom hybridized orbital examples: () the same type of orbital: A.C O2 and SO2 B.C H4 and NH3 C.B eCl2 and BF3 d.2h2 and C2H4 Example 2: is true (example 2: of SO2 and CO2 are true a. is rectilinear structure. B. central atom takes sp hybrid orbitals. The central atom takes hybrid orbitals D ) C. S atoms and atoms do not have lone pairs of electrons. Atoms and C atoms have no lone pair of electron atoms and D. SO2 are v-shaped structures, and CO2 is a straight line junction Example 3: write the following lewis structure of molecules is example 3: write the following lewis structure of molecules (is expressed in short-term bond electronics, small black spots said no bonding in short-term bond electronic speck says not structural formula of bond valence electrons), and points out that the central atom may adopt structural formula of valence electrons And points out that the central atom type of hybrid orbitals may adopt, and predict the geometry of the molecule. The hybridized orbital type and the geometry of the molecule. (1) PCl3 (2) BCl3 (3) CS2 (4) C12O Analysis:... .. .. (1) PCl3: CI P CI. .. CI... .. CI (2) BCl3:... .. .. .. .. .. .. .. (3) CS2: SP3 triangulation. .. SP SP3 straight-line V. SP2 Plane triangle .. .. S = S.. .. .. (4) C12O: Cl O CI:... .. .. .. Complexes theory introduction: complexes theory introduction: experiment 2-1 CuSO4 CuCl2.2 H2O CuBr2 solid color white solution Sky blue green, sky blue NaCl K2SO4 white Colorless KBr white Colorless, Dark brown white Sky blue color Think: the first three solutions are in the sky blue probably rela