阳离子分析实验的经验（Experience in cationic analysis）.docVIP

阳离子分析实验的经验（Experience in cationic analysis） Potassium ion In general, sodium hexonitrocobalate was used for the determination of neutral and microacidic conditions to prevent the decomposition of sodium hexitrocobalate. When the root of ammonium is present, it will be interfered by the standard and may not be observed in practice. Potassium and tartaric acid can be formed precipitate and the precipitation solubility is small, potassium tartrate is one of the few insoluble potassium salt, but not suitable for identification. Because it is easy to produce soluble acid salt, potassium tartrate in hot water can dissolve, dilute acid and alkali can dissolve potassium salt, the actual phenomenon is not obvious. And the dahua laboratory generally does not provide tartaric acid. If the first step is not detected in the first step, the potassium ion can be tested by a single drop test, which can effectively prevent the leak detection Second, the ammonium root In general, the gas chamber method is used in the system. After the addition of ammonia to the system, it is necessary to verify the root of ammonium. Ammonia is highly volatile in hot weather conditions. Tip1: small petri dishes together with big petri dishes to reagent, add 3 drops rapidly after 6 m naoh cover the surface of small dish, otherwise the ammonia volatilization rapidly from the testers, without red, on the water bath heating two minutes, if have ammonium, phenolphthalein test paper should be to become red. If the small surface of the dish is removed, the phenolphthalein test paper will fade quickly due to the presence of carbon dioxide in the air. Tip2: for the production of phenolphthalein test paper, the strip of paper is too long. It should be torn to two, about half a centimeter, and the phenolphthalein drops two drops on both ends, too little to be glued, too much to fall off. Use nail tips to keep it fixed. When covering the small surface of the plate, the action should be light, preventing the test