高中化学3（High school chemistry 3）.docVIP

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高中化学3（High school chemistry 3）.doc

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高中化学3（High school chemistry 3）

高中化学3（High school chemistry 3） 1. Nonmetallic single matter (F2, Cl2, O2, S, N2, P, C, Si) 1. Oxidation: F2 + H2 = = 2HF F2 + Xe (excessive) = = XeF2 2F2 (excessive) NF2 + 2M = = = 2MFn = = 4HF + 2H2O = = 4HF + O2 2 F2 + naoh = = = 2 naf OF2 + H2O + F2 + 2 nacl = = = 2 naf + Cl2 F2 + 2NaBr = = = 2NaF + Br2 + 2NaI = = = 2NaF + I2 F2 + Cl2 (equal volume) = = 2ClF 3 f2 (overdose) + Cl2 = = 2ClF3 7F2 (overdose) + I2 = = 2IF7 Cl2 + H2 = = = 2 HCL Cl2 3 + 2 p = = = 2 PCl3 Cl2 + PCl3 = = = PCl5 Cl2 na + 2 + 2 = = = 2 nacl 3 Cl2 fe = = = 2 fecl3 Cl2 fecl3 fecl2 + 2 = = = 2 Cl2 + Cu = = = CuCl2 Cl2 nabr + 2 = = = 2 nacl + Br2 Cl2 + 2 nai nacl + I2 = = = 2 5 Cl2 + I2 + 6 h2o + 10 = = = 2 hio3 HCL Cl2 Na2S + nacl = = = 2 + S Cl2 + H2S = = = 2 HCL + S Cl2 + SO2 + 2 h2o + 2 = = = - H2SO4 HCL Cl2 HCL + O2 + H2O2 = = = 2 2 O2 + 3 fe = = = = = = Fe3O4 O2 + K KO2 H2S 2 S + H2 = = = = = = S + C CS2 S + Fe = = = FeS cu S + 2 = = = Cu2S 3 S + 2, + zinc = = = = = = Al2S3 S ZnS. Administered N2 + 3 h2 = = = 2 nh3 N2 + 3 mg = = = Mg3N2 N2 + 3 ca = = = Ca3N2 N2 + 3 ba = = = Ba3N2 N2 + 6 na 2 na3n N2 + 6 k = = = = = = 2 k3n N2 + 6 rb3n rb = = = 2 P4 h2 + 6 = = P + 3 na = = = = 4 ph3 Na3P 2 P + 3 zinc = = = Zn3P2 2. Reductive S + O2 SO2 = = = S + - H2SO4 (thick) = = = 3 SO2 + 2 h2o S + 6HNO3 (thick) = = H2SO4 + 6NO2 + 2H2O 3S + 4HNO (sparse) = = 3SO2 + 4NO + 2H2O N2 + O2 = = = 2 no 4P + 5O2 = = = P4O10 (often written as P2O5) 2P + 3X2 = = = 2PX3 (X represents F2, Cl2, Br2). PX3 + X2 = = = PX5 P4 hno3 + 20 (thick) = = = 4 h3po4 no2 + 4 h2o + 20 C + 2F2 = = CF4 C + 2Cl2 = = CCl4 2C + O2 (a little) = = 2CO C CO2 + O2 (enough) = = = = = = C + CO2 CO 2 C + H2O = = = CO + H2 (water-gas) generated 2C + SiO2 = = = Si + 2CO (made of coarse silicon) Si (coarse) + 2 cl = = = SiCl4 (SiCl4 + 2 h2 = = = Si (pure) + 4 HCL) Si + O2 = = = SiO2 (powder) Si + C = = = SiC (emery) Si + 2NaOH + H2O = = = = Na2SiO3 + 2H2 3, dismutation Cl2 + H2O = = = HCl + HClO (acid suppression disproportionation, alkali or ligh