含乙烯基聚碳硅烷陶瓷先驱体的合成及其电子束辐射不熔化研究.PDF

CNIC-01520 CAEP-0069 含乙烯基聚碳硅烷陶瓷先驱体的合成 及其电子束辐射不熔化研究 SYNTHESIS OF VINYL-CONTAINING POLYCARBOSILANE CERAMICS PRECURSOR AND ITS CURING BY ELECTRON BEAM IRRADIATION (In Chinese) 中 国 核 情 报 中 心 China Nuclear Information Centre 1 CNIC-01520 CAEP-0069 含乙烯基聚碳硅烷陶瓷先驱体的合成 及其电子束辐射不熔化研究 许云书 傅依备 楚增勇 宋永才 （中国工程物理研究院，成都，610005 ） 摘 要 通过接枝共聚合反应将环甲基乙烯基硅氮烷引入聚碳硅烷 （PCS ）陶瓷先驱体的分子链上，纺丝成型后用电子束辐照，然后 在高温下热解转化成为性能优良的SiC 陶瓷纤维。结果表明，乙烯 基含量仅为2.33% （质量百分比）时即能有效降低PCS 的辐射不熔 化剂量，并且所得SiC 纤维的氧含量已从18.9%降低至3.3% ，在1600 ℃的高温条件下处理30 min 后纤维的微观形貌仍然保持良好。 2 Synthesis of Vinyl-containing Polycarbosilane Ceramics Precursor and Its Curing by Electron Beam Irradiation (In Chinese) XU Yunshu FU Yibei CHU Zengyong SONG Yongcai (China Academy of Engineering Physics, Chengdu) ABSTRACT Cyclo-methylvinylsilazane was grafted onto the molecular chains of polycarbosilane ceramics precursor through heat co-polymerization. The vinyl- containing precursors were then spun into fibers, irradiated by electron beam, and finally converted into SiC ceramics fibers by high temperature pyrolysis. Results showed that just a small vinyl content of 2.33% could effectively decrease the radiation-curing dose. The oxygen content of the final SiC fibers decreased to 3.3 %, much lower than that of the SiC fibers obtained by pyrolysis of oxidation cured precursors. After heated at 1600 ℃ for 30 min