800合金在300 ℃ naoh和eta溶液中的腐蚀行为 - 金属学报.pdf

第52 卷 第5 期 Vol.52 No.5 2016 年5 月 第599-606 页 ACTA METALLURGICA SINICA May 2016 pp.599-606 800 合金在300 ℃NaOH 和ETA 溶液中的腐蚀行为* 王家贞 王俭秋 韩恩厚 ( 中国科学院金属研究所中国科学院核用材料与安全评价重点实验室, 沈阳 110016) 摘 要 采用动电位极化曲线, 电化学阻抗谱(EIS), SEM, XPS 等分析手段研究了800 合金在300 ℃NaOH 和乙醇胺(ETA) 溶液中的腐蚀行为. 结果表明, ETA 的添加降低合金的腐蚀电流密度, 增大了氧化膜的膜层电阻. 无论是否添加ETA, 800 合 金均为双层膜结构. 未添加ETA 时,合金氧化膜外层富Ni, ETA 添加后氧化膜外层富Cr. ETA 的添加提高了氧化膜中Cr 的富 集程度, 促进了铬氧化物的形成, 增强了800 合金氧化膜的保护性. 关键词 800 合金, 乙醇胺, 动电位极化曲线, 氧化膜 中图法分类号 TG 172.9 文献标识码 A 文章编号 0412-1961(2016)05-0599-08 CORROSION BEHAVIOR OF ALLOY 800 IN NaOH AND ETA SOLUTIONS AT 300 ℃ WANG Jiazhen, WANG Jianqiu, HAN En-Hou Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China Correspondent: WANG Jianqiu, professor, Tel: (024) E-mail: wangjianqiu@imr.ac.cn Supported by National Key Science and Technology Project of China (No.2011ZX06004- 009) and National Basic Research Program of China (No.2011CB610500) Manuscript received 2015-09-19, in revised form 2015-10-30 ABSTRACT Many components in secondary side of pressurized water reactors (PWRs) are made of carbon steels and low alloy steels. The corrosion products produced by the flow accelerated corrosion (FAC) of these com- ponents can deposite on the surface of steam generator (SG) tubes and decrease the heat transfer efficiency of SG tubes. Moreover, the enrichment of foreign ions (e.g. Cl- and Pb2+) occurs with the sedimentation of corrosion prod- ucts and