ZnAl[V10 O28 ] 6- 水滑石在镁合金防腐中的机理研究 - 材料工程.PDF

30 / 2008 12 ZnAl[V O ] 6- 10 28 Study of Anticorrosion Mechanisms on ZnAl[ V 10 O28 ] 6- Hydrotalcite for M Alloy , , , , ( , 150001) YU Xian , WANG Jun, YA NG Lihui, LI Junqin , ZNANG M ilin ( Key Laboratory of Superli ht M aterial and Surface T echnolo y, Ministry of Education, Colle e of M aterials Science and Chemical En ineerin , Har bin En ineerin U niversity , Harbin 150001, China) : N , ICP ; 2 / : , : ; ; ; : O6473; T B37 : A : 2008) Abstract: As an environmentalfr iendly new style pi ment for M alloy corr osion protection, decavan adate ( [ V10 O28 ] 6- ) interlay er ZnA l hy drotalcite ( ZnAl[ V10 O28 ] 6- ) w as pr epared by coprecipitation method, w hich can absorb corrosive anion and release the inhibitor of [ V10 O28 ] 6- ion. T he adsorption 2 and anticorrosion mechanisms of the hydrotalcite w ere investi ated by N adsorptiondesorption, In ductively Coupled Plasma ( ICP) and polarisation curves respectively . T he corrosion protection proper ties for M alloy based on the ZnAl[ V10 O28 ] 6- / epoxy coatin s w ere investi ated by salt spray tes tin . The results demonstrated that the material can afford doubly function of anodic passivity and barrier protection and had excellent corrosion resistant property. Key words: anticorr osion; hy drotalcite; absorb and ionex chan e; M alloy ( LDHs) , [ 1, 2] , , [ 3 , 4] 1 , , , 1 Fi 1 Th e structure