钛酸钠的制备启发以此为模板制钛酸锂.pdfVIP

J O U R N A L O F M A T E R I A L S S C I E N C E 3 8 (2 0 0 3 ) 2907 – 2911 Study on the synthesis and ion-exchange properties of layered titanate Na Ti O 2 3 7 powders with different sizes JUAN YANG ∗,†, DAN LI, XIN WANG, XUJIE YANG, LUDE LU Materials Chemistry Laboratory, Center of Nanoscience and Nanotechnology, Nanjing University of Science and Technology, Nanjing 210094, People’s Republic of China E-mail: yangjuan6347@163.net Layered titanate Na Ti O powders with varying sizes were prepared by solid-state reaction 2 3 7 of Na2 CO3 and TiO2 with different average particle sizes. The structures of the titanates and the products which had undergone H+ and Ag+ exchange were investigated by XRD, TEM and BET analysis. The influence of the particle size of starting material TiO2 on the reaction rate, the particle size and ion-exchange property of the resulting products was studied. It is found that nanometer sized TiO2 facilitates the solid-state reaction and leads to the formation of ultrafine titanate. The H+-exchange property is improved by decreasing the particle size of Na Ti O and the small sized layered titanate can be exfoliated easily by 2 3 7 AgNO3 solution. C 2003 Kluwer Academic Publishers 1. Introduction sizes of the titanates, though this has received little at- A number of layered titanates with interlayer alkali tention. Currently, layered titanates are at micrometer metals have received considerable attention because of size because they are usually prepared via a solid state their potential application in various technologies as reaction at high temperatures (800–1300◦C) with long ion exchangers, adsorbents, photocatalysts and catalyst