外加磁场对掺杂TiO2薄膜光催化活性的影响.pdfVIP

第3O卷 第3期 世界科技研究与发展 V01．3O NO．3 2008年6月 245—248页 WORLD SCI-TECH RD Jun．2008 PP．245—248 外加磁场对掺杂TiO2薄膜光催化活性的影响 尹荔松 范海陆一 周克省 陈永平 谭 敏 (中南大学物理科学与技术学院，长沙410083) 摘 要：利用外加匀强磁场辅助掺杂TiO2光催化降解偶氮胭脂红B溶液，实验探讨了外加磁场强度对Fe 、Ni2 、cu“掺杂TiO2 薄膜光催化活性的影响。结果表明：外加磁场使掺杂Ni“／TiO2、Fe ／TiO2薄膜的光催化活性降低，在磁感应强度为0．7×10I2 T时，催化剂Fe ／TiO2几乎完全失活，光催化降解率低于2．0％，而掺杂0．5％Cu“／TiO2薄膜的光催化活性在磁场辅助下光催 化活性普遍增强，感应强度为1．0×10I2 T时光催化降解率达19．4％，相当于无外加磁场时的1．2倍；理论分析指出，磁场辅助对 掺杂TiO，光催化活性的影响与掺杂离子的磁导率有关。 关键词：TiO，；光催化；磁场；掺杂 中图分类号：TQ316．241 文献标识码：A Effect of Permanent Magnetic Field on the Photo-catalytic Activity of Doped TiO2 Films YIN Lisong FAN Hailu ZHOU Kesheng CHEN Yongping TAN Min (School ofPhysics and Technology，Central South University，Changsha 410083) Abstract：The effects of magnetic field on photo—catalytic degradation of Azocarmine B with Ni 、Fe 、Cu doped TiO2 films were investi— gated．The results indicate that the photo—catalytic activity of Fe ／TiO2、Ni ／TiO2 films are deactivation and the activity of Cu。 ／TiO2 films are reactivation under magnetic field．The degradation rate of Fe”／TiO2 films less than 2．0％ under 0． 7×10～ T magnetic induc— tion．The degradation rate of doped Cu。 ／TiO2(0．5％)film achieves 19．4％ under 1．0×10～T magnetic induction，which is 1．2 times compared with that without applied magnetic field．Theoretical analysis indicates that the effect of permanent magnetic field on the photo—cat alytic activity of doped TiO2 films is determined by the doping ion’S magnetic permeability and the magnetic intensity． Key words：Titanium dioxide；photochemical catalysis；magnetic field；doping 永久磁铁、高斯计，采用Nt—Mdt生产的solver p47型原子力 1 引言