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22 1 2 2005 Acta Mater iae Comp ositae Sin ica Vol122 No11 February 2005 : 1000-3851 ( 2005) 01-0001-05 1 1, * 1 1, 2 1 1 王结良 , 梁国正 , 赵 雯, 吕生华 , 任鹏刚 , 杨洁颖 ( 11 , 710072; 21 , 712081) : A , DSC , , CE , FTIR DSC CTBN , CE , CTBN 15% , 39147% 21192% , , , T GA HDT CTBN , CTBN 0 15% , 407e 383 e : ; CTBN; : TB332; T Q3231 5 : A CYANATE ESTERSMODIFIED BY CARBOXYL-TERMINATED LIQUID BUTADIENE-ACRYLONITRILE 1 1, * 1 ## 1, 2 WANG Jieliang , LIANG Guozheng , ZHAO Wen , LU Shenghua , 1 1 REN Penggang , YANG Jieying ( 11 De artment of A lied Chemistry, School of Sciences, Northwestern Polytechnical University, Xi. an 710072, China; 21 College of Leather Engineering, Shaanxi University of Science and Technology, Xianyang 712081, China) Abstract: Cyanate esters were modified by carboxyl terminated liquid butadiene-acrylonitrile ( CTBN) to im rove their toughness. O timized curing arameters w ere obtained by gel time curves and differential scanning calorimetry ( DSC) of t he systems. Fourier transform infrared s ectrometry ( FT IR) and DSC w ere em loyed to show the curing behavior of the systems. It was observed, by com arison wit h urified cyanate esters, that the addition of CTBN has large influence on t he curing behavior of the systems during lower tem erature, but little during higher tem erature. Scanning electron mi- crosco y ( SEM) w as em loyed to sh