超声_双氧水和亚铁离子体系处理含酚废水研究_赵朝成.pdfVIP

2004 23 1 11 1 1 2 2 赵朝成 , 陆晓华 , 张 英 , 赵东风 ( 1 , 430074; 2 , 25706 1) : 在实验装置上对超声- 双氧水和亚铁离子体系联合 理含酚废水进行了实验研究主要考察了废水初始pH 值初始双 氧水浓度超声功率反应时间等因素对酚去除率的影响实验结果表明: 超声辐射可以在双氧水和亚铁离子体系氧化过程 中起加速反应的作用, 而且随着超声功率的增大, 加速反应的能力增强; 实验条件下废水初始pH 值为4~ 68, 初始双氧水浓 度为140mg/ L 时酚去除效果最佳; 超声- 双氧水和亚铁离子体系 理含酚废水过程中苯酚的降解规律符合表观一级反应 : ; ; ; ; : X703 : A : 1001-3644( 2004) 01-0011-04 Experimental Study on Treatment of Pheno-l containing Wastewater by Ultrasound- Hydrogen Peroxide and Ferrous Ions 1 1 2 2 ZHAO Chao- heng , LU Xiao-hua , ZHANG Ying , ZHAO Dong-feng ( 1Dep t of E nv ir onmental Sc i E ng . , H uaz hong Univ er sity of Science and Tech nology , W uhan 430074, China 2D ep tof E nv ir onmental Sc i E ng . , School of Chem istry and Chemical E ngineer ing , Un iv er sity of P etr ole um, Dongy ing , Shandong 257061, China) bstract: Experimental study on treatment of wastewater ontaining phenol by Ultrasound- Hy drogen Perox ide and Ferrous Ions was arried out with a set of rea tor at different onditions. T he influen e of several different parameters in luding t he initial pH value of w astewater , t he initial on entration of hy drogen perox ide, sound intensity, rea tion time was investigated. The results showed that t he ultrasound an enhan e the rea tion. The removal effi ien y of phenol will be the highest if t he pH value is from 4 to 68 and the init ial on entrat ion of peroxide is 140mg/ L under experimental ondition. The ox idation rea t ion of phenol by Ultrasound-Hydrogen Peroxide and Ferrous Ions follows apparent first order r