滴定分析法（Titrimetric analysis）.docVIP

滴定分析法（Titrimetric analysis） The twelfth chapter titration analysis method Home page Problem analysis Student self test questions Student answer Chapter after Exercises answer Problem analysis [TOP] In case 12-1, take 1.6160 g ammonium sulfate solid, dissolve it with water and transfer to 250 mL capacity bottle for constant volume. Absorb 25 mL, add excess NaOH distillation, and then absorb the resulting NH3 with 40 mL 0.05100 mol L-1 solution, and the remaining H2SO4 is neutralized with 17 mL, 0.09600 mol, L-1 NaOH solution (H2SO4 titration). Calculate the mass fraction of NH3 in the sample. The reaction is 2NH3 + H2SO4 = (NH4) 2SO4. The reaction of (NH4) 2SO4 and NaOH is: (NH4) 2SO4 + 2NaOH = 2NH3 + Na2SO4 + 2H2O The reaction of H2SO4 to NH3 is: 2NH3 + H2SO4 = (NH4) 2SO4 Reverse titration reaction: H2SO4 + 2NaOH = Na2SO4 + 2H2O The formula for calculating the amount of ammonia is derived from the above formula: According to mass fraction: Case 12-2 accurately absorb calcium chloride (Mr = 111) injection 2 mL, dilute with water and add ammonium oxalate to precipitate, calcium oxalate precipitation, separation, after washing, add dilute sulfuric acid to precipitate completely dissolved. Titrate the oxalate out of the solution with C (KMnO4) = 0.02000 mol L-1, using the KMnO4 solution 26.12 mL. The mass concentration of CaCl2 in the injection was calculated. According to the reaction formula involved: Ca2+ + = CaC2O4 N (CaCl2) = n (CaC2O4) = n () 5 + 2 + 16H+ = 2Mn2+ + 10CO2 + 8H2O be so The three order dissociation constants of citric acid (H3Cit) were p = 3.14, P = 4.77, and P = 6.39, 12-3. 0.1000 mol L-1 citric acid solution, titrated with 0.1000 mol L-1NaOH standard solution, will have several titration jumps? What indicators should be used? Solution C x = 0.1000 * 10 - 3.14 = 7.2 * 10-5 10-8 C = 0.1000 * * = 1.7 * 10610-8 104.77 C = 0.1000 * * = 4.1 * 10-8 106.39 Because C * 10-8, c * 10-8, H3Cit solution can be titrated directly to Cit3- by NaOH standard solut