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物理化学 傅献彩(Physical chemistry, Fu Xiancai)
物理化学 傅献彩(Physical chemistry, Fu Xiancai)
Bibliography:
1) Physical Chemistry (Fourth Edition) Journal of Fu et al, higher education press, 1990 edition;
2) physical chemistry (Third Edition), Wang Zhenglie et al., higher education press, 1988
I. examination requirements:
Closed examination, written norms, neat, all the answers are written on the answer sheet, otherwise invalid.
Two, examination content:
1) gas p-V-T property:
A: understand the difference between the ideal gas model, the actual gas and the ideal gas p-V-T.
B: master ideal gas equation of state, Fan Dehua equation, partial pressure, volume concept and application, gas liquefaction and critical properties, critical parameters, comparative parameters, corresponding state principle, compression factor and so on.
2) the first law of thermodynamics:
A: understands systems and environments, states and states, nature, processes and pathways, reversible processes, concepts of work and heat.
B: grasps the important concepts of the first law of thermodynamics, enthalpy, Cp, Cv, and phase change enthalpy, as well as the relation between temperature and temperature. Master the process of simple pVT change, the process of phase change and the calculation of Q, W and calculation of chemical reaction process.
The c: will design a process to calculate the heat, work, temperature, thermodynamic energy, and enthalpy changes in complex conditions.
D: grasps the relation between enthalpy of chemical reaction, enthalpy of phase change and temperature, the application of the first law of thermodynamics to ideal gas and the characteristics of throttling process. The concepts of enthalpy of dissolution, enthalpy of dilution, and enthalpy of ion formation are known.
3) the second law of thermodynamics:
A: master the concepts of Kano cycle and heat engine efficiency. The Kano cycle is shown on p-V, T-S, H-S, and so on. B: understands the representation, essence, Kano theorem, and inference of the second law. Grasp the concept
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