太阳能固定膜光催化灭菌的特性.pdfVIP

第28卷第 3期 环 境 科 学 学 报 Vo1．28，No．3 2008年3月 ActaScientiaeCircumstantiae Mar．，2008 林少华，李田．2008．太阳能固定膜光催化灭菌的特性[J]．环境科学学报，28(3)：484—489 Lin S H．Li T．2008．Disinfection characteristics ofE．coliin a solar photocatalytic reactorwith immobilized catalyst[J]．Acta Scientiae Circumstantiae，28 (3)：484—489 太阳能固定膜光催化灭菌的特性 林少华，李田 同济大学污染控制与资源化国家重点试验室，上海200092 收稿日期：2007—01—23 修回日期：2007-06-09 录用日期：2007-12-12 摘要：以实用型太阳能固定膜光催化中试装置对水中大肠杆菌的灭活特性进行了研究．结果表明，太阳能固定膜光催化灭菌包含光催化灭菌和 阳光直接灭菌的协同作用，光催化杀菌效果优于阳光的直接杀菌效果．环境扫描电镜分析(ESEM)表明，光催化处理对菌体产生了致命性破 坏．光催化灭菌还具有良好的持久性，灭菌处理8 h后，没有出现明显复活再生现象．光催化灭菌速率随循环流速、光强的增大而增大．太阳能 固定膜光催化灭菌技术具有良好的应用前景． 关键词：太阳能光催化；固定膜；大肠杆菌 文章编号：0253-2468(2008)03-484-06 中图分类号：X703 文献标识码：A Disinfection characteristics Of E． coli in a solar phOtOcatalytic reactor with immobilized catalyst LIN Shaohua，LI Tian State Key Lab of Pollution Control and Resource Reuse，Ton~i University，Shanghai 200092 Received 23 January 2007； received in revised form 9 June 2007； accepted 1 2 December 2007 Abstract：The disinfection of Escherichia coli was investigated in a pilot—scale solar photocatalytic reactor with an immobilized catalyst．It was found that the disinfection was caused by the synergistic effect of solar UV irradiation and oxidant species generated by the TiO2 catalyst，and the latter had greater effects than the former．ESEM analysis revealed that the bacterial cells were destroyed by the solar photocatalysis．Further studies showed that the disinfection rate increased with water flow rate and light intensity．It seems that the solar photocatalysis disinfection technique has a promising future in drinking water treatment． Keywords：solar photocatalysis；immobilized catalyst；E．coli 物也具有灭活作用(Rincon et a1．，2004a；Fernandez 1 引言(Introduction)