解读聚羧酸盐高性能减水剂作用机理.docVIP

解读聚羧酸盐高性能减水剂的作用机理 Interpretation of poly carboxylic acid salt, the mechanism of the high performance water reducing agent 聚羧酸盐高性能减水剂是由带有磺酸基、羧基、氨基以及含有聚氧乙烯侧链等的大分子化合物，在水溶液中，经过自在基共聚原理合成的具有梳型构造的高分子外表活性剂。 Poly carboxylic acid salt of high performance water reducing agent is made with a sulfonic group, carboxyl, amino, and containing polyoxyethylene side chain of macromolecular compounds, such as in aqueous solution, after a comfortable base copolymerization principle of synthetic polymer surface active agent with the comb type structure. 合成聚羧酸盐高性能减水剂所需的主要原料有：甲基丙烯酸、丙烯酸、丙烯酸乙酯、丙烯酸羟乙酯、烯丙基磺酸钠、甲基丙烯酸甲酯、2-丙烯酰胺基-2-甲基丙烯酸、甲氧基聚氧乙烯甲基丙烯酸酯、乙氧基聚乙二醇丙烯酸酯、烯丙基醚等，在聚合过程中可采用的引发剂为：过硫酸盐水性引发剂、过氧化苯甲酰、偶氮二异丁氰；链转移剂有：3-疏基丙酸、疏基乙酸、疏基乙醇以及异丙醇等。 Synthesis of poly (carboxylic acid salt of main raw material for high performance water reducing agent are: methyl acrylate, ethyl acrylate, acrylic acid, hydroxy ethyl acrylate, sodium allyl sulfonic acid, methyl methacrylate, 2 - acrylamide - 2 - methyl acrylate, methoxy polyoxyethylene methyl acrylate and ethoxy polyethylene glycol acrylate, allyl ether, etc., can be used in the process of polymerization initiator for: water-based persulfate initiator, benzoyl peroxide, azo diisobutyl cyanogen; Chain transfer agent has: 3 - hydrophobic thin base of propionic acid, acetic acid, ethanol and isopropyl alcohol. 聚羧酸盐高性能减水剂是一种新型减水剂，具有许多突出的优点，但其作用机理目前尚未完整分明，以下是其中的一些观念： Poly carboxylic acid salt of high performance water reducing agent is a new type of water reducing agent, has many prominent advantages, but its mechanism has not yet complete and clear, here are some ideas: 聚羧酸类聚合物对水泥有较为显著的缓凝作用，主要由于羧基充任了缓凝成分，R-COO～与Ca2+离子作用构成络合物，降低溶液中的Ca2+离子浓度，延缓Ca(OH)2构成结晶，减少C-H-S凝胶的构成，延缓了水泥水化。 Poly carboxylic acid polymers of cement have relatively significant retarding effect, mainly because of the carboxyl filled retarded components, R - COO ~ and Ca2 + ions constitutes a complex, reduce the Ca2 + ion concentration in the solution, to delay the Ca (OH) 2 crystal, reduce C -h -s