高浓度含铜废水资材化处理技术之探讨.PDFVIP

高濃度含銅廢水資材化處理技術之探討* Reclaiming Useful Materials from High Copper Containing Wastewater * by Magnetic Separation 1 1 2 3 1 1 2 3 J. Y. Wu W. S. Chen Y. H. Shen M. S. Tsai The purp ose of th is tr eatment process is to provide a r eclaim ing method for tr eat ing h igh copp er concentr at ion wastewater. In the first stage of mineralization, the wastewater is added into a tank with sodium hydroxide solution followed by the addition of Fe3+ ion and heated to 70. The molar ratio pH between Fe3+ and Mt2+ ion is maintained and the pH value of solution is controlled in a strongly alkaline environment . In the inver se mixing method (adding high copp er cont aining wastewater to sodium hydroxide solution), the precipit ation process was carried out in an alkaline solution with pH value pH greater than 12.5, which resulted in simultaneous precipitation of Fe3+, Cu2+, Ni2+ and Zn2+ ions. The reaction of the first stage is complete when the ORP reading remains constant. In the second st age of magnetization reaction , the formation of magnetic ferr ite, Fe2+ ion is added to the solution accompanied while being heated and aerated. Magnetic separation is used for the TCLP solid-liquid separation . Results show that the concentration of copper and heavy mineral ions of the effluent is well below the regulatory standards and the solid products meet the TCLP test standar