水溶液中低温制备高定向排列纳米氧化锌薄膜的研究.pdfVIP

№．3 陕西科技大学学报 Ju轧2008 ·6· JOURNAL OF SHAANXI UNIVERSITY OF SCIENCETECHNOLOGY V0L 26 文章编号：1000-581 1(2008)03—0006—05 LOW-TEMPERATURE FABRICATION OF ZnO NANOARRAYS ON SnO2：F CONDUCTIVE SNBSTRATE USING AN AQUEOUS SOLUTION HU Xiu—lan，YOSHITAKE Masuda，TATSUKI Ohji，KAZUMI Kato (National Institute of Advanced Industrial Science and Technology(AIST)，Nagoya 463—8650，Japan) Abstract：ZnO nanoarrays are successfully fabricated on an anhydrous zinc acetate seed coa— ted SnO2：F substrate by its in situ forced hydrolysis at the initial stage in an aqueous solu— tion without pre-existing ZnO seeds or expensive catalyst．Anhydrous zinc acetate seeds were derived from the low-temperature dehydration of zinc acetate dihydrate spin-coated on the substrate at 65℃ in oven．High_resolution TEM clarified the formation mechanism that in situ forced hydrolysis of an anhydrous zinc acetate seed to ZnO nanocrystals at the initial stage promoted growth of ZnO nanoarrays by heterogeneous nucleation and growth ． In situ forced hydrolysis—assisted technique at low temperature can be useful for the fabrication of optoelectronic devices with low cOst and without using expensive catalyst． Key words：ZnO nanoarrays；aqueous solution deposition；anhydrous zinc acetate：forced hy— drolysis；heterogeneous nucleation and growth a Number：TB383；0782 ．1 Document Code：A 0 Introduction Wurtzite zinc oxide(ZnO)is a wide-band—gap(3．37 eV)semiconductor with high binding energy (60 meV)，it is a realistic candidate for transparent conductive oxides due to its unique optical and elec— tronic pro