乙二醛水溶液纯化研究.PDF

27 1 Vol. 27, No . 1 2006 3 Journal of Hebei University of Science and T ec nology Mar . 2006 : 1008-1542( 2006) 01-0045- 04 李雪刚, 张智勇, 赵地顺 ( 河北科技大学化学与制药工程学院, 河北石家庄 050018) : 乙二醛有多种生产方法, 其纯化对象亦有 不同在乙醛硝酸氧化法生产乙二醛的工艺 中, 其主要待去除成分是硝酸和醋酸介绍了电渗析电去离子技术纯化乙二醛水溶液的过程, 并 与其他纯化方法进行了对比 : 乙二醛; 纯化; 电渗析; 电去离子技术 : T Q0283 : A Study on purification of glyoxal w ater solution LI Xue-gang, ZHANG Z i-yong, ZHAO D-i s un ( College of C emical and P armaceutical Engineering, Hebei University of Science and Tec nology , S ijiaz uang H ebei 050018, C ina) Abstract : T ere are several routes to produce glyoxal, and t e purification tec niques are somew at different. In t e process of producing glyoxal by means of nitric acid oxidat ion, t e main components to be removed in t e product are nit ric acid and acet ic acid. T is paper discusses mainly t e applications of electrodialysis and electrodeionization tec niques to purify glyoxal aqueous solution. Some ot er met ods are also introduced. Key words: glyoxal; purificat ion; elect rodialysis; electrodeionization tec nology , C2 H2 O2 [ 1] , w ( ) 30%~ 40% DEBUS 19 60 , ( BASF) , , , 20 70 , , : , , , 1 t/ a , 1 t/ a 20 70 , 20 90 , , , , , , : 2005-03-23; : 2005- 04-28; : : ( 1981- ) , ,, , 46 2006 , , , , , , , 1 800 t , 1 1. 1 [ 2] , , , (40 ) , , CH3 CHO+ HNO3 CHOCHO+ H2 O+ N2 O; CH3 CHO+ HNO3 CH3 COOH+ NO+ H2 O, CHOCHO+ HNO3 CHOCOOH+ NO+ H2 O, CHOCOOH+ HNO3 COOHCOOH+ N O+ H2 O , , ,