天然黄铁矿吸附废水中Cd_的实验研究.pdfVIP

第 27卷 第 4期 西 安 科 技 大 学 学 报 Vo.l 27 No4 2007年 12月 JOURNAL OF XIAN UN IVERSITY OF SCIENCE AND TECHNOLOGY Dec2007 : 1672 9315( 2007) 04 0576 05 * Cd( ) 端木合顺, 文生燕 ( , 710054) : 分批次实验研究了平衡时间溶液 pH 值Cd( )初始浓度 径对天然黄铁矿吸附废水 中Cd( )的影响实验前利用 XRD衍射确定黄铁矿的特征, 并确定了黄铁矿零电荷点 pHPZC为 64在吸附平衡时间 30 m in, pH 值 60, 即接近零电荷点时对 Cd( )的吸附量最大初始浓 度黄铁矿 径对吸附Cd( )的影响表明, 最大吸附量分别在 Cd( )浓度为 350mg/L和 径为 200目时实验数据与 Freundlich等温线拟合良好初步探讨了黄铁矿吸附 Cd( )的机理研 究表明, 天然黄铁矿可以有效除去有毒有害重金属 Cd( ), 是处理工业废水的优良吸附剂 : 黄铁矿; pHPZC; Cd( )吸附; 等温线 : X 7035 : A Adsorption of Cd( ) from aqueous solution onto pyrite DUANMU H eshun , WEN Shengyan (D ep tof Geo logy and E nv ironm ental E ng ineer ing, X ian Un iv er sity of Sc ience and Technology, X ian 710054, Ch ina ) Abstract: The physicochem ical factors such as equilibrium tmi e, solution pH, initial concentration of Cd( ), particle size and temperature that control the adsorption of Cd( ) from aqueous solutions on to pyrite have been investigated through batch expermi entsPrior to this study, pyritewas characterized through chem ical and XRD analysisThe point of zero charge, pHpzc was found to be 64The equi librium tmi ewas 30m in at the solution pH of 60The pH influence ofCd( ) adsorptionwas remark able and maxmi um metal uptakewas observed at 60which is closer to pH pzcConcentration and parti cle size dependence ofmetal uptake indicates that saturation of pyrite surface by adsorbate occurs at an initialCd( ) concentration of 350mg /L and particle size 200The empirical Freundlich isotherm fits the expermi ental data quitewellThework reveals that natural pyrite is a ver