超细凹凸棒土机械化学法表面改性及其在LLDPE中的应用.pdfVIP

第 卷第 期 32 3 Vol.32 No.3 非金属矿 年 月 Non-Metallic Mines May, 2009 2009 5 超细凹凸棒土机械化学法表面改性及其在LLDPE中的应用 张智宏  石亚超  刘雪东 （江苏工业学院化学化工学院，常州 213016 ） 摘  要  使用搅拌球磨机，利用机械化学法，以硬脂酸作为改性剂，对凹凸棒土进行超细粉碎与表面改性一体化试验，优化工艺条件下改性 凹土粉体的活化指数可达0.97，粉体中位径d50 为0.64µm。凹土改性前后的红外谱图对比说明硬脂酸与凹土粉体表面产生化学吸附。将改性凹 土作为填充剂加入线性低密度聚乙烯(LLDPE)，在改性凹土的填充量为6% 时，拉伸强度比同填充量的未改性凹土提高28.3%，断裂伸长率提高了 12.2%。截面形貌分析图谱表明，改性凹土和基体树脂间建立起牢固的界面结合，边缘过渡平滑，复合材料相关力学性能得到改善。 关键词  凹凸棒土 机械化学法 表面改性 线性低密度聚乙烯 力学性能        TQ32 ;TD97 A 1000-8098(2009)03-0023-04 中图分类号： 文献标识码： 文章编号： Mechanochemical Surface Modification of Ultrafine Attapulgite and Its Uses in LLDPE Zhang Zhihong Shi Yachao Liu Xuedong ( College of Chemistry and Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016 ) Abstract Integrating ultrafine grinding with mechanochemical surface modification of attapulgite by stirring-type ball mill and using stearic acid as modifier were investigated. Activation index of modified attapulgite was 0.97, and median diameter was 0.64µm under the optimum technical and operation conditions. The infrared spectra of attapulgite clay and modified attapulgite showed that surface modification was feasible. When the content of modified attapulgite was wt6% inserted into LLDPE as stuffing, the tensile strength and breaking elongation increased respectively by 28.3% and 12.2%. Surface topographies at sample section showed that fastness combina