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囊泡形成和破坏的动力学Kinetics of Vesicle Formation and Breakdown
2007 65 Vol. 65, 2007
20 , ACTA CHIMICA SINICA No. 20,
· ·
*
( 361005)
(SDS)(DTAB)
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Kinetics of Vesicle Formation and Breakdown
ZHOU, Wen-Ting XU, Xiao-Ming LAN, Qin HAN, Guo-Bin*
(State Key Laboratory for Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and
Chemical Engineering, Xiamen University, Xiamen 361005 )
Abstract A combination of stopped-flow, transmission electron microscopy and dynamic light-scattering
techniques has been used to study the kinetics of vesicle formation and breakdown as well as the mechanism
of vesicle formation and breakdown in DTAB/SDS aqueous solutions. The results show that the process of
vesicle formation can be modeled as a sequence of distinct processes: mixed micellesflexible stick-shaped
aggregatesnon-equilibrium vesiclesequilibrium vesicle system, and the evolution of particle dispersion
degree appears to be a periodical change of “monodispersitypolydispersity”. In addition, the kinetic
analysis shows that the process of vesicle formation lasts for a long time. However, the activation energy of
vesicle formation is not too high, which implies that the control procedure of the process is independent of
activation energy. In contrast to the process of vesicle formation, vesicle breakup to mixed micelles appears
to be a rapid process.
Keywords vesicle; surfactant; stopped-flow method; effective packing parameter
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