影响Langmuir-Blodgett 膜中缺陷畴区的因素Factors to Affect .PDF

2008 年第 66 卷 化 学 学 报 Vol. 66, 2008 第 8 期, 959～963 ACTA CHIMICA SINICA No. 8, 959～963 ·研究论文· 影响 Langmuir-Blodgett 膜中缺陷畴区的因素 邓穗平 欧阳健明* (暨南大学 生物矿化与结石病防治研究所 广州 510632) 摘要 采用扫描电子显微镜(SEM)和荧光显微镜研究了基片种类、温度、制膜参数(如 Langmuir-Blodgett 膜沉积压、压 膜速度、提膜速度等)和 LB 膜层数对 LB 膜中缺陷畴区的影响及其对尿石矿物——水草酸钙(COM) 晶体生长的指导作 用. LB 膜中的缺陷畴区可以诱导圆形 COM 沉积图形形成, 但在石英基片上的图形数量只有云母基片上的 5%左右. 制 膜温度由 25 ℃降低至 18 ℃时, 出现非圆形 COM 沉积图形, 尺寸亦有增大的趋势. 随着沉积压从 2 mN/m 增大到 10 mN/m, 云母基片上圆形 COM 晶体沉积图形数量减少, 沉积图形尺寸趋于均一, 非圆形图形数量增加. 随着压膜速度 增加, 膜中缺陷增加. 当 LB 膜的层数由 1 层增加到 2, 3, 5 层后, 其诱导的 COM 图形数量逐渐减少, 尺寸也相应减小, 即单层 LB 膜的缺陷比多层膜的多, 且更容易受到基片的影响. 关键词 LB 膜; 单分子膜; 草酸钙; 生物矿化; 尿石 Factors to Affect Defective Domains in Langmuir-Blodgett Films DENG, Sui-Ping OUYANG, Jian-Ming* (Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632) Abstract The effect of a series of parameters on the defects in Langmuir-Blodgett (LB) films and the ef- fect of these parameters on the formation of calcium oxalate monohydrate (COM) crystals were investigated by scanning electronic microscopy (SEM) and fluorescence microscopy. The investigated parameters in- cluded the kinds of substrates, temperature, deposition parameters (such as deposition surface pressure, compression rate, dipping speed) and the layers of LB films. The defective domains in LB films could in- duce the formation of circular patterns of COM crystals. The number of such p