TEP和TPP用作锂离子蓄电池电解液阻燃剂的研究 Study on TEP and TPP as flame-retardant additives in electrolytes for Li-ion batteries.pdfVIP

TEP禾II TPP用作锂离子蓄电池电解液阻燃剂的研究 周代营，， 左晓希，， 谭春林，， 李伟善， 卢 雷t， 刘建生： (1．华南师范大学化学与环境学院，广东广州510006；2广州市天赐高新材料科技有限公司，广东广州510600) 摘要：在1mol／L 阻燃电解质。研究了该电解质的电导率、阻燃性以及使用该电解质的锂离子电池的充放电性能和安全-陛。结果表明，虽 然TEP和TPP的使用降低了电解液的电导率。但对电池充放电-陛能影响不大，而且最著提高了电解液的阻燃-陛能及 电池的安全性。 关键词：锂离子蓄电池；阻燃剂；安全性 912．9 002—087 中图分类号：TM 文献标识码：A 文章编号：1 X(2007)09—0687—03 onTEPTPPasflame—retardant Study and additives in for batteries Li—ion electrolytes ZHOU Xiao—xil，TANChun-linl，LIWei—shanl，LULeil，LIU Dai—yin91，ZUO Jian—shen92 ChinaNormal (1．DepartmentofChemistry,SouthUniversity’GuangzhouGuangdong510006，China； Tianci New Material TradeCo 2．GuangzhouHigh TechnologyLtd．，GuangzhOUGuangdong510600，China) Abstract：Flame-retardedforLi-ion were in1mol／L 1 solution electrolytesbatteryprepared LiPFd(EC+DMC)(1：1by flame-retarded con— usingtriethylphosphate(TEP)andtriphenylphosphate(TPP)as andtheflame-retardedofthe andthe ofLi—ion ductivity ability electrolytes，thesafety charg—dischargeperformance withthese werestudied．Theresultsshowthattheflame-retardedofthe and battery electrolytes ability electrolyte the ofLi-ion are withthe oftheadditivesandthe batteryimproved application safety significantly charge—discharge ofLi-ion islessinfluencedthe ofthe arereduced．