复合聚酰亚胺滤毡的制备及其滤除PM2.5颗粒.PDFVIP

第 16卷第5 期 过 程 工 程 学 报 Vol.16 No.5 2016 年 10 月 The Chinese Journal of Process Engineering Oct. 2016 复合聚酰亚胺滤毡的制备及其滤除 PM2.5颗粒  尚磊明， 李 蕾， 李艳香， 杨传芳 ( 中国科学院过程工程研究所绿色过程与工程重点实验室，北京 100190) 摘 要：以260~350 g/m2 的芳纶无纺毡为基底层、40~60 g/m2 的耐高温无纺布为保护层，通过静电喷雾将高温粘合剂均匀涂布 在基底层上，再采用静电纺丝技术将直径 150~400 nm 的可溶性聚酰亚胺(P84)纳米纤维均匀纺制其上，附上保护层，热压固化使 3 层材料紧密结合，得到三明治结构的耐高温纳米纤维复合过滤毡，用其去除模拟气溶胶(粒径 0.3~10 m 的NaCl)颗粒. 结果表 明，复合滤毡粘结强度超过 1000 kPa，粘合剂对基底性能影响较小，少量纳米纤维可有效提高材料的过滤效率，对粒径2.0 m 以上和 1.0~2.0 m NaCl 颗粒的过滤效率分别达 100%和 99.5% 以上. 关键词：静电纺丝；聚酰亚胺；PM2.5 颗粒；过滤效率；纳米纤维；复合滤毡 中图分类号：TQ340.6 文献标识码：A 文章编号：1009606X(2016)05086208 DOI: 10.12034/j.issn.1009-606X.216144 Preparation of Composite Polyimide Filtration Filter and Its Application in PM2.5 Removal SHANG Lei-ming, LI Lei, LI Yan-xiang, YANG Chuan-fang (Key Lab. Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China) Abstract: A composite felt with sandwiched structure was prepared by evenly depositing basis of 150~400 nm electrospun soluble polyimide (P84) nanofibers on substrates of aramid nonwoven fabrics of 260~350 g/m2 . The substrates were pre-sprayed electrostatically with high-temperature adhesives to bind the nanofibers. Another protective layer made of high-temperature nonwovens with basis of 40~60 g/m2 was used to shield the nanofibers. The composite was then hot-pressed to gain the binding strength as the adhesives solidified, to remove the simulated dusts, 0.3~10 m NaCl aerosols. The results showed t