化工设计摘要.docVIP

1. Process Design 1.1Raw Material and Products The raw material of this project is C4 hydrocarbon mixture, whose composition as follows: Table1-1 Composition of Raw Materials Composition Fraction/wt% i-butane 0.4 n-butane 5.8 1-butylene 37.27 Cis 2-butene 4.0 Trans-2-butene 5.16 i-butene 1.17 1,2-butadiene - 1,3-butadiene 45.3 1-butyne - 2-butyne - Vinyl acetylene 0.7 C5 0.1 C3 0.1 Table1-2 Composition and Specification of Products Item Test method National standard/% Company standard/% Quality Production（kt/a） 1,3-butadiene GB/T13291-2008 ≥99.50（wt%） 99.7%(wt%) excellent grade 163 propylene GB/T≥99.60（V/V） 99.7%(V/V) excellent grade 145 ethylene GB/T7715-2003 ≥99.90（V/V） 99.9%(V/V) first-class 32 Process Scheme This project consists of two sections: butadiene extraction and raffinate C4 catalytic cracking. The section of butadiene extraction is to extract the butadiene from the C4 hydrocarbon mixture raw material, which consists of double extracting, double stripping and butadiene purification. The section of catalytic cracking consists of catalytic cracking and separating, which produced polymer grade propylene and ethylene. Figure1-1 Butadiene Extraction Produce PFD Figure1-2 Raffinate C4 Cracking Produce PFD 1.3Main Innovation of Process (1).C4~C8 olefins can be reacted in the ZSM-5 catalyst. So the C4~C5 olefins can be recycled to the raw material, which improves the yield coefficient of propylene. (2) We found the best conditions of catalytic cracking reaction from related patent. But the best dimension of the reactor is unknown. For that, we simulated three different aspect ratios of reactor by using Comsol Multiphysics. From the result of simulation, we got the best dimension of reactor. Figure 1-3 The Result of Simulation by Comsol Multiphysics (3).The control parameter can be optimized by Aspen Dynamics, which has guiding significance for the practical operation. Figure 1-2 The Simulation of Propylene Coupling Tower 2. Energy-s