卡尔.费休库仑滴定法测定原油水含量.pdfVIP

KEM Application Note No. EKCA-10379 Coulometric Karl-Fischer Titration Kyoto Electronics Manufacturing Co., Ltd. Data No. LN47-10348 Moisture of Crude oil -Summary- Checked the possibility of measuring moisture of Crude oil with MKC-520, and good repeatability was obtained. -Measuring instrument- Main unit: MKC-520 Coulometric KF moisture titrator Electrode: M-713 Twin platinum electrode #433-0006 Inner burette -Reagent- Anolyte: Coulomat AG(60mL) + Xylene(40mL) Catholyte: Coulomat CG -Measurement method- Preparation: (1) Fill the titration cell with the anolyte and the inner burette with the catholyte. (2) Pretitrate for dehydration. Measurement: (1) Place sample in the titration cell and start the measurement. -Equation- Moisture (ppm): ((Data-Driftt-Blank)/(Wt1-Wt2))F Data : Measured water content (g) Drift : Drift before measurement (g/s) t : Measuring time(s) Blank : Blank value (g) Wt1 : Tare including sample weight (g) Wt2 : Tare including residual weight (g) F : Factor (1.00) -Standard method- Karl Fischer method -Ambient conditions- Temperature: 23 C R. Humidity: 67 % Weather: Rain No. EKCA-10379 -Measurement parameter- -Printout data- [ T i t r a t i o n ] Method 1 t(stir) 0 s t(wait) 15 s t(max) 0 s Drift Stop : Rel