锂电池容量分析（Lithium battery capacity analysis）.docVIP

锂电池容量分析（Lithium battery capacity analysis） Analysis of attenuation of lithium battery capacity Lithium ion battery embedded reaction occurs between two electrodes with different embedding energy, and to obtain the best performance, battery capacity than the two host electrode should keep a balanced value. In the lithium ion battery, the volume balance indicates that it becomes positive to the mass ratio, namely: Gamma m = m + / - = Δ xC - / Δ yC + Type in C refers to the theory of coulombs capacity of electrode, Δ x, Δ y refers to embed the cathode and anode respectively the number of stoichiometric lithium ion. It can be seen from the above equation that the mass required by the poles is greater than that of the corresponding coulomb capacity and its respective reversible lithium ions. Generally speaking, the lower quality is less than the incomplete utilization of the negative electrode materials; The larger mass ratio may be a safety hazard due to the negative electrode being overcharged. All in all, the optimal quality of the battery is the best. For the ideal li-ion battery system, the capacity balance does not change during its cycle, the initial capacity in each cycle is a certain value, but the situation is much more complicated. Any can produce or consume lithium ion or electron side effects could lead to battery capacity balance changes, once the battery capacity balance changes, this change is irreversible, and can be accumulated through many times cycle, serious impact on battery performance. In lithium ion battery, in addition to lithium ion to take off the embedded REDOX reaction occurs, there are a lot of side effects, such as electrolyte decomposition, active substances dissolved, lithium metal deposition, etc., as shown in figure 1. Arora [3], such as the process and the half cell discharge capacity attenuation curve contrast, so we can clearly see the battery work when the possibility of capacity attenuation and the reasons, as shown in figure 2. I