1图一为染料、Clay与不同比例Clay之FT-IR叠图.DOC

鹽基性染料的改質及其性質研究 黃國賢、陳炯博、吳維章 摘要 本實驗主要利用鹽基性染料本身帶有正電荷基團與Clay進行陽離子交換，而將鹽基性染料改質，並利用相關儀器如FTIR、XRD、TGA、UV-Vis等進行分析與檢測。經實驗結果得知，鹽基性染料因陽離子交換插層到Clay中，而改質過的鹽基性染料其熱性質會隨著Clay的添加量而呈較穩定，同時發現改質過的染料其色光並不會因為添加Clay而改變，但其吸光度會隨著Clay添加量之增加而漸減。另外改質過的染料其耐日光堅牢度較未改質染料為佳。 關鍵字：鹽基性染料、蒙脫土、XRD、熱穩定性 一、前言 有機-無機複合材是近幾年來的研究重點。有機-無機複合材料因其綜合了有機物和無機物各自的優點，並且可以在力學、熱學、光學、電磁學和生物學等方面賦予材料許多優異的性能。其中2：1型層狀矽酸鹽蒙脫土因其突出的離子交換吸附性能，非常適合有機物插層而備受青睞[1]。 鹽基性染料係具有-NH2、-NHCH3、-N(CH3)、-NHC2H5、-N(C2H5)2Bentonite clay K-10 (purched U.S.A. ACROS), Acetone, Isoproapnol (IPA), the two chemicals were reagent grade and supplied Japan Reagent Industry Corporation。The woolen fabrics employed as the test products were pretreated by the washing and grabbing process, which was supplied by Shun Fu tai Industrial Company, Ltd., Taiwan, 48Nw × 48Nw, ends (52) and picks (44); 符號 定義 Clay Clay Dye 精製鹽基性染料 D2C1 2g鹽基性染料+0.1gClay D2C2 2g鹽基性染料+0.2gClay D2C5 2g鹽基性染料+0.5gClay D2C8 2g鹽基性染料+0.8gClay D2C20 2g鹽基性染料+2.0gClay D2C30 2g鹽基性染料+3.0gClay D02C30 0.2g鹽基性染料+3.0gClay Measurement and Analysis of composite materials FT-IR/ATR spectra of the dyes were recorded with a Bio-Rad Digilab FTS-200 spectrometer using an MCT detector. A diamond crystal was used as internal reflectance element. Single beam spectra were the result of 64 scans. The spectral resolution was 4 cm-1. A Bruker-AXS D8 was used for X-ray powder diffraction (Parallel beam optics, Cu-target, scintillation counter, sampler changer with rotation). The samples were run with 40kV, 100mA, 2-60o theta/2theta,0.01o stepsize and 5sec counting time. The thermal resistance of samples were measured by DuPont 2200 weight-loss analyzer. The 5-10 mg samples were placed in alumina crucibles and test with a thermal ramp over a temperature range of 30-600℃, at a heating rate of 20℃/min under nitrogen flow speed of 20cc/min, after which their initial decomposition temperature (IDT) was obtained. The λmax、color strength and color cast of the composite materials were measurement by UV-