Sc掺杂M型钡铁氧体烧结过程中的相变及磁性研究.pdfVIP

Applied Physics 应用物理, 2016, 6(11), 265-271 Published Online November 2016 in Hans. /journal/app /10.12677/app.2016.611033 Phase Transition and Magnetic Properties in the Forming Process of Sc Doped M-Type Hexaferrite Hao Zhou, Rujun Tang* Jiangsu Key Laboratory of Thin Films, College of Physics, Optoelectronics and Energy, Soochow University, Suzhou Jiangsu th rd th Received: Nov. 9 , 2016; accepted: Nov. 23 , 2016; published: Nov. 29 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Open Access Abstract Sc doped M-type hexaferrite BaFe10.2Sc1.8O19 was prepared with the conventional solid state reaction method. The phase and magnetic property transition processes in the sintering process of M-type hexaferrite BaFe Sc O have been investigated. Results show that the spinel phase BaFe O and 10.2 1.8 19 2 4 ion-deficient M-type hexaferrite dominate when sintering temperature is lower than 1000˚C. The M-type hexaferrite BaFe10.2Sc1.8O19 appears above 1050˚C and does not become a single phase until 1200˚C. Both the remanence ratio and coercivity of the samples decrease with increasing sintering temperature and drop to nearly zero above 1200˚C. However, the saturation magnetization of the samples increases with increasing sintering temperature until 1050˚C and then decreases. The magnetic property transition process agrees well with the phase transition process. The above re- sults show that incorporation of Sc3+ into the M-type he